几种类型矿物对磷的吸附对比研究-环境科学专业论文.docxVIP

Comparative Comparative study of adsorption of phosphate on several types of mineral Ahstract IIl ordel-to decrease the more and more serious eutrophication ofreservoirs．this article studies the adsorption of phosphate in simulated water7埘m concentrations from 5mg／L to 50megL by several typical types of mineral-iron hydroxides／oxides(goethite，hematite， synthesis goethite and amorphous ferric hydroxide)and attapulgite(attapulgite， hydrothermal attapulgite and dolomite—attapulgite)from the adsorption thermody7namics and adsorption kinetics． Freundlich adsorption istherm approximatively can be availabed to adsorption of phosphate on goethite and hematite，the linear relationship of Langmuir adsorption isotherm is beuer with adsorption of phosphate on synthesis goethite and amorphous ferric hydroxide．The AG of goethite and hematite are-15．08～一14．94 and·14．55～13．24kJ／mol individually,these indicate adsorptions of phosphate on goethite and hematite are physical adsorption．The AG of synthesis goethite and amorphous ferric hydroxide are-28．44～ 一26．08 and一31．73～·27．68kJ／mol individually,these indicate adsorptions ofphosphate on synthesis goethite and amorphous ferric hydroxide are not only involve physical process， but also involve chemical adsorption．The whole process of adsorption of phosphate on goethite and hematite ate more in line with the Bangham’s kinetics equation．The diffusion ofphosphate ions in the pore size is divided into four phases：rapid adsorption stage；gently stage；again，accelerated phase；flat stage again． The adsorptions of phosphate on attapulgite，hydrothermal attapulgite and dolomite-attapulgite are suitable to Freundlich adsorption istherm．The AG of attapulgite， hydrothermal attapulgite and dolomite-attapulgite are all negative，and the adsorption of phosphate is physical adsorption process．In the range ofthe researching concentrations，the adsorption kinetics data ofphosphate on them Call be used to meet the pseudo—second-order model．The content of dolo