几种稀土掺杂化合物的上转换性质及其对TiO2光催化性能的增强-凝聚态物理专业论文.docxVIP

II II 和 360nm 的紫外光，当 Tm3+离子浓度为 1%时强度最强。以上转换蓝光为研究对象我 们用 980nm 和 808nm 作为激发源，发现当两光源功率固定时，共激发强度远远大于两 光源单独激发之和，我们认为这主要是两光源共同激发下的协同效应引起的，在一定 程度上论证了氙灯下上转换样品与 TiO2 混合物对甲基橙的降解规律与 980nm 激发下的 强度变化规律不一致的现象。 关键词：上转换；发光；能量传递；TiO2 III III Abstract With the development of the society and economic, many nations are faced with a tremendous set of environmental problems. Groundwater contamination is likely to the primary one of human contact with toxic chemicals. As a semiconductor photocatalysis TiO2 has been applied to a variety of problems of environmental due to its physical and chemical stability, cheapness, relatively high catalytic reactivity and so on. However, for its broad band gap (3.2eV) the ultraviolet light is required to irradiate the TiO2 photocatalyst. The ultraviolet light only takes 3-4% of the sunlight. Hence, it restricts the application of TiO2. Much research work has been done to improve its catalyticactivity in visible light for example codoping with transition-metal ions, codoping with non-metal ions, combination with narrow band-gap semiconductors and so on. These methods indeed extend the range of absorption wavelength of TiO2, however, catalytic ability cound not be improved. The electron hole pairs generated by various wavelength lights are different. Their oxidation reduction potentials are different. To keep higher oxidation potential, the ultraviolet lights must be used to excite TiO2. Therefore, upconversion phosphor which can convert lower-energy photons into higher-energy ones satisfy the demand of TiO2. In this thesis, the luminescence properties of upconversion phosphor and the photocatalytic activity of it mixed with TiO2 is studied. The main works are presented as follows: The upconversion luminescence of YAlO3:Er3+ phosphor co-doping with different Gd3+ concentration has been investigated under the excitation of 980nm and 532nm diode lasers. Different upconversion emissions wavelengths at 646, 550 and 380nm under 980nm excitation and 850，655，4