环氧树脂基轻质吸声材料-化学工程专业论文.docxVIP

环氧树脂基轻质吸声材料量的降低；两种国产玻璃空心微珠相比，利用B型微珠制备的复合泡沫塑料压缩强 环氧树脂基轻质吸声材料 量的降低；两种国产玻璃空心微珠相比，利用B型微珠制备的复合泡沫塑料压缩强 度、压缩模量、冲击强度均优于A型；B型玻璃空心微珠表面经偶联剂处理后，材 料的压缩强度、压缩模量和冲击强度得到较大提高；将聚氨酯引入环氧树脂基体可 以在不增加密度的同时，使材料的机械性能得到一定程度的改善：加大玻璃空心微 珠的填充量，可以制备密度在O．40-0．559／crn3水平的复合泡沫塑料，此时材料的压 缩强度和压缩模量较低。 研究了PU／EP材料的动态力学性能与复合泡沫塑料的声学性能。对动态力学性 能的研究表明，PU的引入可以使材料的阻尼温域增宽，同时阻尼峰向低温移动； 阻尼峰值温度随测试频率的降低有向低温移动的趋势；EP储能模量～频率主曲线上 的阻尼区出现在极低的频率上，PU的加入可以使其向高频移动；PU／EP材料在 16--22kI-Iz的频率范围内阻尼性能较差，声衰减常数较低，声速在2000---3500m／s的 范围内随频率单调增大；1,4．BD／TMP引入基体可以使声衰减常数稍有增加，相应 声速略有降低；基体树脂中溶解了vDC，AN／st共聚树脂后，复合泡沫塑料的声衰 减常数基本不变，声速有所降低；基体树脂中vDC，AN／St共聚树脂的引入有利于 实现材料与水介质的阻抗匹配。等体积的A型与B型玻璃空心微珠填充制备的复 合泡沫塑料具有相近的声衰减常数，略低于纯环氧树脂。采用酚醛空心微珠／A型国 产玻璃空心微珠复合填充制备的复合泡沫塑料声衰减常数得到成倍的提高；复合泡 沫塑料的声速较纯环氧树脂均有所提高；空心微珠的填充同样有利于材料与水介质 的阻抗匹配；作为一种闭孔型的泡沫塑料，酚醛空心微珠填充制备的复合泡沫塑料 在0．2~3．5kI-Iz范围内吸声系数在0．1~o．25的范围内波动。 关键词：环氧树脂；聚氨酯；改性；VDC／AN／St共聚物空心微珠；机械性能；阻尼； 声学性能 U 浙江大学硕：t学位论文Abstract 浙江大学硕：t学位论文 Abstract Syntactic foam which USed under water with excellent mechanical and acoustic attenuation properties，based on epoxy resin(EP)filled with hollow microspheres was studied at present thesis．Firstly,on the base resin,highly damping polyurethane(PU)Was added into EP,not only toughened the base resin，but also improved the damping properties．Secondl％vinylidene chloride(VDC)／acrylonitrile(AN)／styrene(St)copolymer microsphere with property improvement was carried out,the effect of VDC／AN／St copolymer introduction into base resin on acoustic properties was studied．Finally, syntactic foam with acoustic attenuation property was prepared by using internal hollow glass microspheres and phenolic microspheres，mechanical and acoustic properties of syntactic foam were studied． The modification effects of different PU types based on glycols and isocyanates respectively wefe compared．PU prepolymers based on PPG-A,PPG-C，IIP·A reacted with isophorone diisocyanate(IPDI)was synthesized firstly and then introduced into epoxy network by additive reaction with epoxy and cure reaction of epoxy．It is found that