混凝土内钢筋阻锈剂的扩散及腐蚀抑制行为研究-应用化学专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II II ABSTRACT Corrosion inhibitor is an important measure to protect steel from corrosion in concrete. At present, for the assessment of rebar corrosion and corrosion inhibitor, more attention is paid on the engineering application. Traditional electrochemical methods are mostly confined to the overall electrochemical process of steel, and rarely the uneven corrosion. This thesis studied the initiation and evolution of local corrosion of rebar under concrete by 5×20 array wire beam electrode(WBE) in space and time. By the help of diffusionelectrolytic cell, 3% NaCl solution permeated into the concrete sample in a certain direction, to speed up the corrosion of WBE in dry and wet cycles. Each electrode of WBE was weakly polarized to a constant value, and simulated the evolution of corrosion area along with Cl- penetration and dissolved oxygen diffusion by the anodic current distribution of WBE. Adding corrosion inhibitor(DMEA or NaNO2) on one side of concrete sample, we observed the evolution of anodic current distribution of WBE with inhibitor molecule penetration, to discuss the different inhibitors migration rate on the interface of electrode/concrete and the recovery capacity of corroded area. The results show that Fe2+ ions from a corroding wire electrode diffuse out through pores in the mortar, then react with OH- ions and O2 in pore solution, forming insoluble corrosion products Corrosion products accumulate mainly in the micro pores along the steel/mortar interface, the resulting volumetric expansion gives rise to the propagation of cracks and a further inclusion of aggressive species, which would exacerbate the corrosion of rebar. When corrosion products spread to a vicinal uncorroded(passive) wire electrode, it would initiate pitting corrosion of the passive wire electrode due to the high Cl- ion level around it, since the corrosion products have a strong Cl- ions adsorption and cathodic depolarization ability；As a mi