铝合金大气腐蚀室内加速试验研究-材料学专业毕业论文.docxVIP

中文摘要中文摘要 中文摘要 中文摘要 本论文采用连续盐雾试验、周浸试验以及循环盐雾试验，对航空 工业中广泛应用的LC4包铝、LYl2包铝、LC4去包铝和LYl2去包铝 四种铝合金的大气腐蚀进行了室内模拟加速试验研究。采用ACM仪对 试验环境中的腐蚀电流一时间曲线进行了监测，为加速试验对户外暴 露试验的模拟性评价提供依据。对上述三种加速试验分别进行了腐蚀 动力学规律分析，腐蚀产物层的宏观、微观形貌分析以及成份分析。 通过带锈试样在NaCl溶液中的极化曲线测量，对锈层的阻滞性 能进行了分析；通过对带锈试样在NaCl溶液中阻抗谱的分析表明腐 蚀介质在溶液中的传递过程中存在扩散过程，证实了锈层对基体金属 的保护作用。 以万宁地区的户外暴露试验作为参比对象，对上述加速试验的模 拟性与加速性进行了分析得出：对LC4包铝合金和LYl2包铝合金而 言，周浸试验与万宁地区的暴露试验相关性比连续盐雾试验要好；对 于LC4去包铝和LYl2去包铝合金，循环盐雾试验与万宁地区的暴露 试验相关性最好，其次为周浸试验，再次为连续盐雾试验。 关键词：铝合金室内加速试验腐蚀动力学分析腐蚀形貌与成份 分析电化学研究户外暴露试验相关性 AbstractABSTRACT Abstract ABSTRACT In this thesis，for four kinds of aluminum alloys，LC4 aluminum alloy with Al and without Al clad．IY 1 2 aluminum alloy with AI clad and without clad which were widely used in aeronautic industry,the in—door accelerated tests including continuous salt spray，cyclic salt spray and cyclic immersion test were carried out．The corrosion current-time curves were measured by means of atmospheric corrosion monitor(ACM)， which can provides evidence for evaluating the simulation of accelerated test． For the three tests above，the COrrOSiOn kinetic analysis，morphology and composition of the corrosion product and protective character of corrosion layer was investigated．111e protective property of corrosion product layer was studied by polarization curves measurement．The results of A．C impedance measurement revealed that the transfer of corrosive medium is controlled by diffusion process，SO the corrosion product layer has good protection to the matrix． According to the weight loss data from Wanning out—door exposure site，the simulation and acceleration of different accelerated tests were analyzed and the concluded correlation was given． As for LC4 and LY 1 2 aluminum alloy with A1 clad．the cyclic immersion test has beaer correlation with out-door exposure test at Wanning exposure site than continuous salt spray；As for LC4 and LY 1 2 aluminum alloy without A1 clad，the correlation with the out—door exposure test at Wanning should be in the sequence belo