煤聚合物共混材料热稳定性研究-矿物加工工程专业毕业论文.docxVIP

诱导和引发的作用，从丽促进聚合物的降解，降低其热稳定性。通过TG分析，获得 诱导和引发的作用，从丽促进聚合物的降解，降低其热稳定性。通过TG分析，获得 了相应的动力学参数。由动力学参数的变化进一步证明了煤的存在改变了聚合物的 热降解机理。 关键词：煤／聚合物共混材料：热稳定性；动力学；降解机理：可控降解 研究类型‘：应用基础 Subject：Study Subject：Study on the Thermal Stability of Coal／Polymer Blends Specialty：Mineral Processing Engineering Name ：Hu Lihua(Signature) 匕＆虹 Instructor：Zhou Anning(Signature) Abstract Coal／polymer blends are synthesized by three kinds of coal(Tongchan Xujiagou Coal，Shenfu”1 Coal and Huayingshan Lushuidong Coal)and three kinds of polymer matrix(LDPE，LLDPE，HDPE)．The thermal stability and thermal oxidation stability of the samples were investigated by means of TG and DSC， respectively．Three kinds of coal have different effect on polymer stability，for thermal stability，the effect degree are in agreement with the aromaticity of coal． The structure，melt index and crystallinity of matrix al so have important effect for the blends thermal stability．The effect degree order are：LDPELLDPEHDPE． The coal have same effect on thermal and thermal oxidation stability of LDPE and LLDPE，but contrary on the HDPE．When coal concentration1 Owt％，the thermal stability of the blends were decreased，especially when coal concentration was 5wt％．Study shown that different assistants contribute to different effects on the thermal stability of the blends．It was depend on the structure and effect of assistants．So the coal，coal content；the structure and properties of matrix；the structure and effect of assistants are the key factors to affect thermal stability blends．The difference of these factors affect on thermal stability of blends provide base for blends’S control degradation．Base on the FTIR of thermal decomposltlon products and the result of preference，a irregular broken chain jnitiaIcd froC radjCal chain reaction mechanism was assumed for the thermal degradation and thermal oxidation of the blends．Coal participates in all process of chain initiation，chain communication and chain termination．The effect of coal mainly incarnat