镁合金金属型涂料的研究-材料加工工程专业毕业论文.docxVIP

IV IV 不适合作镁合金铸造涂料的高温粘结剂；以电熔氧化镁作耐火粉料的涂 料比以轻质氧化镁作耐火粉料的涂料有着更好的粘结性。 导热性研究表明：浸入法测涂料热导率试验装置简单，操作简便， 可以用来测量涂料的保温性能。通过温度时间曲线，可以直观的反应涂 料的导热性能，浸入法还可以定量地得到不同温度下涂料的热导率。涂 料热导率越小，采用这种涂料得到的试样的晶粒平均尺寸就越大，晶粒 大小可以定性的描述涂料的导热性能。 关键词：镁合金，金属型铸造涂料，悬浮性，流变曲线，流变模型，热 导率 PAGE PAGE VI STUDY OF PERMANENT DIE COATING FOR MAGNESIUM ALLOYS ABSTRACT There is no suitable permanent die casting coating for magnesium alloy in present industrial application. Permanent die coating for magnesium alloys has been investigated by choosing suitable refractory powders, suspensions, and binder in this paper. The causes and resultant of reaction between refractory powders and magnesium alloy melt, as well as the causes of binder failure have been analyzed. The rheological property and thermal conductivity have been tested and an appropriate rheological model was established. The results showed that, magnesium oxide could be used as refractory powders of permanent die coating for magnesium alloys. High bauxite would react with magnesium alloy melt at high temperature, which leaded to the failure of the coating and the reaction products were Mg2Al3 and Mg2Si. The reaction area increased with increasing pouring number. The coating with addition of inhibitor decreased the reactivity and the life time could be prolonged with increasing inhibitor up to 6wt.% . Result of suspend ability showed that, the best ratio of suspensions was: bentonite (3%), CMC (0.2%), P (0.3%) and the suspend rate was 100. Result of rheological property showed that, the modified Casson model could fit the rheological curve exactly, and characterize suspension property and thixotropy of the coating. In the modified Casson model, τ 0 could be used to characterize the stability of suspending system of the coating. Larger τ 0 indicated better suspendability. Ratio of τ 0 and η∞ could be used to characterize the cutting dilutability of the coating and used to characterize the time dependability. τ 0上 ? τ 0下 τ 0上  could be Result of binde