固体氧化物燃料电池阴极数学模型与性能分析.PDF

26 卷 4 期 中 国 电 机 工 程 学 报 Vol.26 No.4 Feb. 2006 2006 年2 月 Proceedings of the CSEE 2006 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2006) 04-0082-06 中图分类号：TM911; TM910 文献标识码：A 学科分类号：48010 固体氧化物燃料电池阴极数学模型与性能分析 史翊翔, 蔡宁生 (清华大学热能工程系，北京市 海淀区 100084) Solid Oxide Fuel Cell Porous Cathode Micro Modeling and Performance Prediction SHI Yi-xiang, CAI Ning-sheng (Department of Thermal Engineering, Tsinghua University, Haidian District, Beijing 100084, China) ABSTRACT: A micro model of a solid oxide fuel cell (SOFC) 算，并研究了混合导体颗粒尺寸、氧气利用率、电极厚度、 porous LSM/YSZ (Strontium-doped LaMnO3 / Yttrium 孔隙结构参数对电极极化的影响。模拟结果对电极微观结构 stabilized Zirconia) cathode was developed. The model coupled 优化及电池运行提供了一定的理论指导。 the intricate interdependency among the ionic conduction, 关键词：热能动力工程；固体氧化物燃料电池；多孔电极； electronic conduction, gas transport phenomenon and 传递；数值模拟；交换电流密度 electrochemical processes. All forms of polarization losses were considered. To improve the model generalization, active 1 引言 three-phase boundary (TPB) was expressed as a function of 随着燃料价格的不断上涨以及全球范围内污 electrode micro structure parameters (porosity, coordination [1] 染物排放标准的逐步提高 ，燃料电池这种新能源 number, contact angle, etc), and exchange current density was [2-8] 技术受到国内外研究者的广泛关注 。与其他类型 treated as a function of cell temperature and oxygen