光助纳米铁还原CrVI的研究.PDF

中国环境科学 2014,34(10) ：2562~2567 China Environmental Science 光助纳米铁还原 Cr(VI)的研究 * 任学昌 ,徐丽凤,杜翠珍,王 拯,刘鹏宇,常 青 (兰州交通大学环境与市政工程学院,甘肃 兰州 730070) 摘要：采用液相还原法制备了纳米铁,并用 X 射线衍射仪(XRD)、扫描电镜(SEM)对其晶体结构、形貌特征进行了表征.以Cr(Ⅵ)为模拟污 染物,中压汞灯作为光源,考察了不同投加量、不同 pH 值等条件下光照对纳米铁还原 Cr(Ⅵ)的影响.结果表明:制备的纳米铁具有很高的反 应活性,粒径约为 7.6nm,呈球形,可在空气中自燃.在 25℃、Cr(Ⅵ)浓度为 20mg/L 、pH=7±0.5,加入 0.1g 的纳米铁,光照 60min 后 Cr(Ⅵ)的还 原率达到 62.3%,而无光照时 Cr(Ⅵ)的还原率仅为 27.6%,说明光照对 Cr(Ⅵ)的还原具有明显的促进作用.当纳米铁投加量较大时,纳米铁对 Cr(Ⅵ)的还原速率大于光照对其产生的影响.反应液pH 值对 Cr(Ⅵ)还原速率的影响较光照对其产生的影响显著.在紫外光的照射下,纳米铁 中电荷可能在诱导下作受迫振荡,与吸附分子发生电荷传递是光照促进纳米铁还原 Cr(Ⅵ) 的主要原因. 关键词：纳米铁；光照；Cr(VI) ；还原 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2014)10-2562-06 * Reduction of Cr (Ⅵ) in water under the condition of photon and nano-iron. REN Xue-chang , XU Li-feng, DU Cui-zhen, WANG Zheng, LIU Peng-yu, CHANG Qing (School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China). China Environmental Science, 2014,34(10)：2562~2567 Abstract ：Nanoscale zero-valent iron (NZVI) was synthesized in aqueous solutions by reduction of Fe3+ with NaBH . The 4 crystal structure and morphology features of the samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), respectively. The reduction rate of the Cr(Ⅵ) was investigated to understand the effect of irradiation of medium pressure mercury lamp on reduction of Cr(Ⅵ) with NZVI, and the effects of irradiation under the conditions of different dosages and pH values. The experimental result showed that nano iron has high reaction activity, and its particle size was about 7.6nm and spontaneously flammable in air. With the