锂空气电池二氧化锰催化剂的制备及性能研究-化学工程与技术专业毕业论文.docxVIP

万方数据 万方数据 哈尔滨工业大学工学硕士学位论文 文中的掺杂和混合催化剂都没有提高材料的催化性能。 关键词：空气电极催化剂；二氧化锰；四氧化三钴；复合催化剂 - II - 哈尔滨工业大学工学硕士学位论文 Abstract Cathode catalyst is a decisive factor in the development of lithium air batteries . Most of the existing high efficiency catalyst are precious metal catalyst. However, precious metal is limited and expensive. Transition metal oxides as cathode catalyst has been widely concerned because it is cheap and easy to prepare. In this paper, we focus on manganese oxide, cobalt oxide, cobalt oxide-manganese oxide composite ORR catalytic performance in neutral electrolyte. The air diffusion electrode is first selected as working electrode in electrochemical tests. But the conductivity of air diffusion electrode is low. Besides, manual electrode repeatability is not good. We choose the catalyst modified glassy carbon electrode as the material testing electrode. The LSV curve appeared ORR current pesk at around -0.6V, at which the current density represents the catalyst performance. In this paper, electrostatic spinning method is used to prepare manganese dioxide, and electric catalytic properties is studied. MnO2 can not be abtained through the electrostatic spinning method, so hydrothermal method is used to prepara manganese dioxide. Beta MnO2 is prepared with ammonium persulfate as the oxidant of hydrothermal method. Reaction temperature is 120oC、140oC、160oC and 180oC respectively, reaction time is 6h、12h and 24h respectively. When the reaction temperature is 120oC, the material shows lowe XRD diffraction peak and the morphology looks like blocks. Under the rest of the reaction temperature, materials are beta MnO2 nanowires. When the reaction temperature is 140oC and reaction time is 12 h, the best catalytic properties is abtained, the current density is mA·cm-2. In order to compare catalytic properties of alpha MnO2 and beta MnO2, manganese oxide is prepared with potassium permanganate as oxidant. Same experiments about reaction temperature and reaction tim