缓释型聚羧酸减水剂的合成与缓释机理研究_ 毕业论文.doc

沈阳建筑大学毕业论文 沈阳建筑 毕业论文 毕 业 论 文 题 目 缓释型聚羧酸减水剂的合成与缓释机理研究 学院专业班级 材料化学09-1班 2013年6月10日 摘要 随着建筑行业的发展，工程应用中对减水剂的要求逐步提高,满足不同施工要求及应用特性的聚羧酸减水剂相继研发。缓释型聚羧酸高效减水剂具有缓慢释放其分散作用的特性，可以达到使混凝土的流动性逐渐增大的效果，既能防止新拌混凝土的泌水，又能确保混凝土施工时具有良好的工作性能，并且可以避免高温运输造成的混凝土坍落度损失过快现象，保证了混凝土的工作性能、力学性能和良好的耐久性能，是符合特殊施工要求的新型聚羧酸减水剂。 本课题首先研究制备了一系列分散及保持性能良好的普通聚羧酸减水剂作为基础体系，并通过对羧酸根离子保护与释放机理的研究及实验，在此体系的基础上确定以羧酸二甲酯为主要缓释组分，进而对该缓释体系进行优化，最终得到性能优良的缓释型聚羧酸高效减水剂。 采用红外光谱等检测方法对缓释型聚羧酸高效减水剂分子进行相应的结构性能表征，明确了缓释型聚羧酸高效减水剂的吸附进程并对反应配比及反应条件对目标减水剂的分子量和分子量分布的影响进行了分析。 通过对不同水泥相容性、减水剂的饱和掺量、混凝土坍落度保持和力学性能实验，明确了目标缓释型聚羧酸高效减水剂的掺量、工作性能和强度。证明实验制备的缓释型聚羧酸高效减水剂在应用中具有良好的缓释效果。 本课题减水剂最终效果可使水泥1h前后扩展度17/18到24/24，水泥水化热放热峰成功被推迟数小时，用水掺量下降20％，减水效果良好。 关键词：缓释；聚羧酸减水剂；羧酸衍生物；水解  ABSTRACT The requriment of the super plasticizer applied in construction increases with the development of construction industry, new super plasticizers was studied to meet various construction requirements and application characteristics. The slow-release polycarboxylic acid based super plasticizer offers a slow release of it’s dispersion actions to achieve the effect that the flowability of the concretee increases gradually. It can both prevent the bleeding of the fresh concrete, ensure the operating property and avoid the evaporation of the mixing water caused by transport in hot weather. So the concrete may have a good workability, mechanics performance and durability.Therefore, the slow-release polycarboxylic acid based super plasticizer is a new type product that applys to special construction requirement. The study preparaed a basic polycarboxylic acid based super plasticizer reaction system with good dispersion and flowability retain properties first. Through the study and experiments on the protection and releasing mechanisms for carboxylic acid ions,it selected dimethyl itaonate as the releasing component, And then optimized the system to get the objective slow-release polycarboxylic acid based super