硫化型NiMo柴油加氢催化剂及制备工艺研究-化学专业论文.docxVIP

摘 摘 要 加氢脱硫工艺是生产超低硫柴油的关键技术，高性能的加氢脱硫催化剂是其核心之 一。论文以了．氧化铝为载体，采用等体积分步浸渍制备了一系列NiMoS／3,．A1203催化剂， 并对催化剂的物化性质进行表征，同时对催化剂的选择性加氢脱硫性能进行了评价。主 要研究了加氢脱硫催化剂的表面性质和制备方法对催化剂活性及选择性的影响，并对催 化反应的工艺条件进行了优化。 研究结果表明，组分Ni的引入提高了催化剂活性组分在载体表面的分散程度，且 Ni含量会影响催化剂活性相的结构。随着Ni含量的增大，MoS2片层长度减小，活性 相的分散度提高，从而催化剂的加氢脱硫的活性和选择性提高。 考察了催化剂的制备方法对其催化性能的影响。研究表明，催化剂的活性与其浸渍 顺序有关，先浸渍铜酸铵溶液比先浸渍硝酸镍水溶液制备的催化剂活性高。用钼酸铵的 配体溶液代替钼酸铵的水溶液，并在管式炉中焙烧制备的催化剂，其活性有明显提高。 在压力2MPa，温度3000C，空速10h_和氢油体积比为300：1的反应条件下，当金 属负载量为26wt％(以NiO+M003计)，Ni／(Ni+Mo)原子比为O．3时，催化剂 NiMoS／),．A1203的脱硫率可达到87％以上，对BP的选择性达到91％。催化剂的活性和 选择性随反应温度的升高而增大。对于硫化态催化剂NiMoS／1,．A1203，不需要进行预处 理，直接进料即可。 关键词：二苯并噻吩，活性，催化剂，活性相，制备方法 Study Study of Sulfided NiMo Catalysts and Preparation Process for Diesel Hyd rotreati ng Ren Hongwei (Chemisity) Directed by Prof．Wang Fangzhu Abstract Depth hydrogenation was the feasible way to reduce sulfur in diesel．In this paper, NiMoS／7-A1203 catalysts were prepared by pore volume impregnation methods step by step． The catalysts were characterized by different analysis methods，and the activity were measured in a high pressure flow micro-reactor．It was investigated that the preparation methods and surface properties of the HDS catalysts could influence the active phase and activity of NiMoS／7-A1203 catalysts． The results showed that Ni could improve the dispersion degree of active component of the catalysts on carder surface，and Ni content could influence structure of the MoS2 active phase for the catalyst．The slab length of MoS2 and the stacking degree of MoS2 could be affected along with the increase of Ni content．The length MoS2 slabs would reduce and the active phase dispersion degree would increase by increasing the content of Ni．In the while， the activity and selectivity of hydrodesulfurization catalyst increased． And it were investigated that the preparation methods of catalysts could influence the activity and selectivity of catalysts to some degree．The results showed that the impregnating order could influence the activity of catalyst．