湿筛分离技术用於现地受重金属污染土壤之可行性与健康风险评价.doc

濕篩分離技術用於現地受重金屬污染土壤之可行性與健康風險評估 Feasibility of Wet Sieving Separation on Heavy Metals Contaminated Soils and their Health Risk Assessment 研究生：周昱銘 Jhou, Min-Yu 指導教授：薩支高 Sah Jy-Gau 【摘要】 重金屬進入土壤環境後，常會因土壤顆粒之比表面積大小，導致土壤吸附重金屬濃度不同。本研究探討濕篩分離技術用於現地受重金屬污染土壤之可行性與健康風險評估，土壤樣品採集於台灣南部兩個已被公告之污染場址以及南部某公園、中部某受污染農田四處土壤，以濕篩法先將粗顆粒與細顆粒分離，對不同粒徑之顆粒進行重金屬全量分析、型態分布及有機質含量測定。土壤顆粒分離後再配合0.1 N HCl萃取，期望增加重金屬之去除率達整治標準。最後以健康風險評估判斷本試驗供試場址對附近居民造成之危害。 研究結果顯示，供試土壤經濕篩法顆粒分離後，可看出重金屬濃度隨著粒徑大小而不同，但因污染場址特性不同，大部分粗顆粒重金屬濃度並未如預期會低於土壤管制標準。於分離後進行0.1 N HCl萃取，發現已有部分供試土壤之重金屬濃度能符合現今法規標準，且萃取效果與重金屬之強鍵結型態(有機態與殘餘態)所佔比例成反比。 以第一層次健康風險評估計算得知，南部兩個已公告之污染場址以及南部某公園之危害指數均大於1，因此必須進一步求得整治目標進行整治。經計算後發現危害指數愈大，整治目標愈嚴格。最後可行之建議是以土地分類或分級管理角度，訂定不同整治目標可有效整治此類場址。 關鍵詞：重金屬、0.1 N HCl萃取、濕篩法、健康風險評估 【Abstract】 Many studies showed the heavy metals concentration of soil particles would be varied by size and specific surface area. We are interesting in this feasibility of wet sieving separation on heavy metals contaminated soils and their health risk assessment. The soil samples were got from two contaminated sites that had been announced as remediation sites by EPA Taiwan, a park in southern Taiwan and a contaminated farmland in central Taiwan. We used wet sieving technology to separate coarse and fine soil particles and investigate the total concentration of heavy metals, organic matter in different particle size. For higher removal efficiency of heavy metal, we extracted soil particles by using 0.1 N HCl also. Finally, we estimated the risk of contaminated sites by using health risk assessment. The results show soils have different relationship between particle sizes and concentration of heavy metals. Heavy metal concentration of all the coarse particle are higher than control standards. Using 0.1 N HCl to extract soil particles, we found the heavy metal concentration of some samples can fit the regulation. Soils with the higher strong bounded forms (organic form and residual form heavy metals), the lower removal effic