高分子材料研究方法-光谱分析.ppt

反应流程图 偶氮苯结构： * ppt课件 * ppt课件 * ppt课件 * ppt课件 N2吸附解吸附典型IV型（中孔），比表面 积为30.3m2/g， BJH模型：孔径在2-4nm IV型 2-4 nm 孔径测试 * ppt课件 * ppt课件 * ppt课件 (1) (2) 经计算，紫外光和可见光下的扩散系 数分别为1.47×10-12 cm2/s 和2.12×10-12 cm2/s，在紫外光下扩散系数增加了44.2% n＜0.5，为Fickian 扩散 蒸馏沉淀聚合法制备单分散双响应中空微球 Ritger and Peppas 7.8h 11.6h * ppt课件 2.4 Infrared Spectroscopy Vibration and IR Spectroscopy Fourier Transform Infrared (FTIR) Spectrometer Relations between Molecular Structures and IR Spectra IR Spectra Analysis Quantitative Analysis Applications on Polymers * ppt课件 2.4.1 Vibration and IR Spectroscopy Vibration Degrees of freedom: 3N-6 (3N-5, for a linear molecule) Vibrational Modes: Bond stretching: symmetrical / asymmetrical Bond bending: out-of-plane bending (wagging or twisting) / in-plane bending (rocking or scissoring) * ppt课件 * ppt课件 * ppt课件 2.4.1 Vibration and IR Spectroscopy IR Spectroscopy Absorption spectroscopy: 4000 ~ 600 cm-1 The selection rule: changing the dipole moment Absorption at the fundamental frequency / the multiple frequency / the combinational (sum / difference) frequency * ppt课件 2.4.2 Fourier Transform Infrared (FRIR) Spectrometer Dispersive Spectrometers Using monochromators (prisms or gratings) and slims Data in the form of frequency profiles Low sensitiveness and slow scanning speed * ppt课件 2.4.2 Fourier Transform Infrared (FTIR) Spectrometer Fourier Transform Infrared (FTIR) Spectrometer A kind of nondispersive spectrometer Components: light source / moving mirror / fixed mirror / beamsplitter / sample cell / detector Data: the interferogram High sensitiveness and rapid scanning speed * ppt课件 * ppt课件 2.4.3 Relations between Molecular  Structures and IR Spectra * ppt课件 2.4.3 Relations between Molecular  Structures and IR Spectra Factors Influencing Characteristic Frequencies of Functional Groups Internal factors Directing effect Conjugating effect Tension in rings Hydrogen bond Coupling effect * ppt课件 Directing effect * ppt课件 Conjugatin