城市垃圾焚烧飞灰重金属药剂配伍稳定化实验研究.docVIP

城市垃圾焚烧飞灰重金属药剂配伍稳定化实验研究 第1卷第lO期 2007l0J 环境工程 ChineseJournalofEnvironmentalEn~ineerin Vo1.1.No.10 0ct.2OO7 城市垃圾焚烧飞灰重金属药剂配伍 稳定化实验研究 刘元元王里奥林祥崔志强罗宇胡刚 (1.重』人大学■峡席区生态环境教育部重点实验审,重庆400045; 2.重庆大学资源及环境科学学院,重庆400044;3.重庆巾铜梁县环境保护局,重』人402560 4.深圳市宝安区城管办,深圳518100) 摘要以琶从巾寓含的Pb和zn为卜{标苇会属,对飞灰巾重金属药剂艇伍稳定化效果了实验研究.选用EDTA, NaS,NaHPO等稳定化约剂和pH值控制,首先将试剂单独投加飞耿中测定重金属浸出浓度,分析各试剂的稳定化效果; 然后通过系列试验观察现象,确定试剂最优投加顺序;最后,按照试剂性质制定4个配伍方案,按照最优投加顺序投加试 齐『J,测定分析各个配伍案的稳定化效果.结果表明:pH值保持在弱碱性(10左右),重金属稳定化效果较好.EDTA二 钠,NaHPO和Nas重金属稳定化效果明显,而有机试剂EDTA二钠稳定化效果明优于NaH,PO和Na,s;稳定化药剂 投加顺序以NaS,EI)TA-钠,NaHPO顺序投加处理效果为最佳;配伍方案4处理效果日』】优于他方案,可以实现稳定 化约剂配仉相合,提高飞从中重金属稳定化效果,同时减少有机螯合剂的使用晕,从而降低处理成本. 关键词城市圾乜厌焚烧重金属无害化处理药剂 中图分类号X705文献标识码A文章编号1673—9108(2007)10—0094—06 Experimentalstudyofthestabilizationofheavymetalsinmunicipal solidwasteincinerationflyashbychemicalagentmatching LiuYuanyuanWangLiaoLinXiangCuiZhiqiangLuoYuHuGang (1.KeyLaboratoryoftheThreeGorgesReservoirRegion’sEco—environment,MinistryotEducation,ChongqingUniversity.Chongqing400045 2.FacultyofResourcesandEnvironmentalSciences,ChongqingUniversity,Chongqing400044; 3.EnvironmentalProtectionBureauofTongliangCounty,Chongqing402560; 4MunicipalAdministrati~,eOfficeofBao’anDistrJe!.Shenzhen5】8】00) AbstractWithtakingheavymetalsPbandZnasthetargetheavymetals,threeagentsofEDTA,Na2S andNaH2PO4andpHvaluecontrolareusedtoexploretheefficiencyofchemicalagentstolimittheleachingof heavymetalsfromflyash.Atfirsttheagentsareaddedintoflyashataspecificrateseparatelyandthestabiliza— tionefficiencyataspecificmassratiotoflyashcanbeobtainedthroughmeasuringtheleachingconcentrationof heavymetals;then,throughseriesexperimentsandsedimentobservation,thesequenceofaddingagentscanbe optimized;finally,basedonthepropertyofchemicalagents,4plansofagentmatchingaremade.Afteradding agentsintheoptimaladdingsequence,theleachingconcentrationsofheavymetalsaremeasuredandthestabili— zationefficiencyofeachmatchingplancanbeanalyzed.Itcanbeconcludedthat:whenpHvaluestaysat10, thestabilizationofheavymetalswillbeeasier.EDTA,NaH2PO4a