有机凝胶自组装模板制备纳米材料.pdfVIP

《化学通报》在线预览版 有机凝胶自组装模板法制备纳米材料 1 2 1* 3 * 常雪灵 ，杨亚江 ，杨祥良 ，马永梅 (华中科技大学1 2 3 生命科学与技术学院 化学系 武汉 430074 ； 中国科学院化学研究所 北京 100080) 摘要 利用溶胶-凝胶聚合过程人工模拟生物矿化进程的技术，已经融入无机材料和超分子有机 化学的研究领域。小分子有机凝胶因子在溶剂中发生自组装，形成多种形态的有机凝胶超分子结构， 以其为模板，经过溶胶-凝胶过程，可以诱导转录形成各种形态的纳米材料。本文介绍了，利用有 机凝胶因子自组装结构为模板，制备形态可控无机材料的研究进展及模板结构诱导转录的两种可能 机制。 关键词 有机凝胶 模板诱导 纳米材料 Preparation of Nano-materials by using Self-assembly of Organogel 1 2 1* 3 * Chang Xueling , Yang Yajiang , Yang Xiangling , Ma Yongmei 1 2 ( College of Life Science and Technology, Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074; 3 Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080) Abstract The design of artificial models of “biomineralization” processes utilizing sol-gel polymerization has become a research branch of inorganic materials research and supramolecular organic chemistry. The self-assembled superstructures of low molecular weight organic gelators are used as versatile building blocks in organogels and as templates for sol-gel transcription into nano-structural materials. The use of self-assembled organic superstructures in the creation of novel inorganic materials with controlled morphologies is focused on and two mechanisms for forming nano-structural materials by the template method are illustrated in this paper. Keywords Organogel, Induced template, Nano-structu