多功能基共改性聚甲基三氟丙基硅氧烷织物整理剂的合成及应用_图.docVIP

郝丽芬, 安秋凤, 许 伟, 王前进 (陕西科技大学教育部轻化工助剂化学与技术重点实验室, 陕西西安 710021 摘 要:利用丙烯酸十八醇酯 、 端烯丙基聚氧乙烯醚 、 烯丙基缩水甘油醚与聚甲基 (3,3,3-三氟丙基 /甲基含氢硅氧烷的硅氢 加成反应 , 制备了一种新型十八酯基 /聚醚 /环氧基共改性聚甲基三氟丙基硅氧烷 (PFSEAS,并考察其在棉纤维织物上的应用效果 . 用红 外光谱 (IR、 核磁共振氢谱 (1H NMR 及场发射扫描电镜 (FESEM表征其结构及研究其在棉纤维表面的成膜性 . 结果发现 :PFSEAS能在 纤维表面形成一层光滑且具有良好疏水性的膜 , 整理后的棉织物与水的静态接触角最高可达 129.2°, 易去污等级达 5级 .PFSEAS 整理对 棉织物的白度影响不大 , 并可使其柔软度增加 . 关键词:改性聚甲基三氟丙基硅氧烷 ; 防水 ; 易去污 ; 织物后整理 中图分类号 :TQ610.4+8 文献标识码 :B 文章编号 :1004-0439(201104-0033-04 多功能基共改性聚甲基三氟丙基硅氧烷 织物整理剂的合成及应用 Synthesis and application of multi-functional groups modified 3,3,3-trifluoropropyl polysiloxane fabric finishing HAO Li -fen, AN Qiu -feng, XU Wei, WANG Qian -jin (Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology, Xian 710021, China Abstract :A novel stearyl/polyether/epoxygroups co-modified 3,3,3-trifluoropropyl polysiloxane (PFSEASwas synthesized by hydrosilylation of stearyl acrylate (SA,allylpolyoxyethylene ether (AEM-12, allylglyeidyl ether (AGEand polytrifluoropropylhydromethylsiloxane (PFHMS.Its application performance on cotton fabric was inve -stigated. The chemical structure of PFSEAS was characterized by infrared spectrum (IRand proton nuclear mag -netic resonance (1H NMR. The film morphology of PFSEAS on cotton fiber surfaces was observed by field emit -ting scanning electronic microscopy (FESEM.The results showed that PFSEAS could form smooth and hydropho -bic film on the fiber surface. The soil release grade of treated fabrics was grade 5, and the biggest static contact angle of water could reach 129.2°. PFSEAS finish had little effect on the whiteness of cotton fabric, and the soft -ness of the treated cotton fabric was enhanced. Key words :modified 3,3,3-trifluoropropyl polysiloxane; water repellent; soil release; fabric finishing 收稿日期:2010-04-28 基金项目:浙江省重大科技专项 (优先主题 工业项目 (2008C11113 ; 陕西科技大学自然科学基金项目 (ZX09-10 资助; 陕西省教育厅自然科学 计划项目 (2010JK442 作者简介:郝丽芬 (1978-,女 , 河北石家庄人 , 讲师 ,