表面活性剂改性活性炭对高氯酸盐的吸附和再生.pdfVIP

中国环境科学2012，32(3)：461-466 ChinaEnvironmentalScience 表面活性剂改性活性炭对高氯酸盐的吸附和再生 陈维芳+，林淑英，程明涛(上海理工大学环境与建筑学院，上海200093) 能力通过吸附穿透曲线来比较．结果表明，未改性活性炭对高氯酸盐几乎没有吸附．CTAC改性则能显著提高活性炭对高氯酸盐的吸附能力． 对高氯酸盐的吸附能力．1mol几HCI溶液的化学再生的效率在95％左右，再生后的活性炭能重复使用．水蒸汽热再生则能有效恢复活性炭的 孔径结构I高氯酸盐在高温下降解得到完全去除，但再生后的炭必须重新改性后才能再次使用． 关键词：表面活性剂；十六烷基三甲基氯化铵；活性炭；高氯酸盐：吸附 中图分类号：X703 文献标识码：A 06 文章编号：1000—6923(2012)03—0461 of surfactant·modifiedactivatedcarbonandits Adsorptionperchlorateby regeneration．CHENWei—fang’，LIN ofEnvironmentand of forScienceand Shu—ying，CHENGMing-tao(School Architecture，UniversityShanghai Environmental Science，2012，32(3)：461～466 Technology,Shanghai200093，China)．China Abstract：Cationicsurfactant chloridewas to anactivated an modify cetyltrimethylammoniumemployed toenhanceAC’S for curveswere beforeandafter adsorption attempt perchlorate．Breakthroughcompared Non-modifiedAChad little for modification AC’S very capacityperchlorate．CTACgreatlyimproved WaSresilient ininfluent as anions，suchN03。，S04+， addition，adsorptioncapacity againchanges pH．However,interfering Si042‘andP04’，showed for resultedindecreasein removal．Activatedcarbon competitionadsorption，which perchlorate was whenitreached of95％WasobservedwhenACwas regenerated breakthrough．Aregenerationefficiency 1 mol／LofHClsolution．Andactivatedcarbonwasabletobereused after regeneratedby directly