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*N96770 微奈米統計力學 * 上課時間: 上課地點 : 國立成功大學工程科學系越生講堂 (41X01教室) 參考資料 微奈米統計力學 Supplement on Quantum Statistical Mechanics Free Particle in a Box First consider a particle m that translates freely between two walls of distance L : Schr?dinger equation of the system : ? : wave function of the particle Ex : energy of the system ? : Hamiltonian operator h : Planck’s constant Periodic boundary conditions : L x m ……… (1) Substitution of the boundary condition gives A = 0. General solution of Eq.(1) : Substitution of the boundary condition gives eigenvalu
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