极性基团协同效应原理在氧化锌矿石.docxVIP

ADDIN CNKISM.UserStyle极性基团协同效应原理在氧化锌矿石 捕收剂开发中的应用现状 刘文刚，赵亮，刘文宝，段浩 （东北大学 资源与土木工程学院，辽宁沈阳，110819） 摘要：多极性基团之间协同作用对捕收剂的捕收性能和选择性具有重要影响，基于极性基团间的协同效应来开发新型、高效的浮选药剂已成为国内外研究的热点。本文对极性基团间协同作用在强化氧化锌矿石捕收剂浮选性能中的应用情况进行了总结和分析。结果表明，多键合作用可以显著提升捕收剂对含锌氧化矿物的捕收性能和分选效率，极性基团间电子效应则可改善捕收剂的物理化学性能提高浮选效率。深入研究极性基团协同作用机理，对精准调控捕收剂浮选能力具有重要意义。 关键词：氧化锌矿石，多极性基团，协同作用，捕收剂 Application Status of the synergetic effect principle between multipolar groups on the development of zinc oxide ore collectors Wengang Liu Liang Zhao Wenbao Liu Hao Duan （School of Resources and Civil Engineering, Northeastern University, Shenyang, Liaoning 110819, China） Abstract：The synergetic effects between multipolar groups have the important impact on the collecting capacity and selectivity of collectors. Based on the synergetic effects between multipolar groups to develop original and effective flotation reagents has become research hotspot at home and abroad. In this paper, application situations of the synergetic effects between multipolar groups strengthening the efficiency of zinc oxide ore collectors are analyzed and summarized. The results showed that multi-bonding interaction can significantly improve the collecting property and separation efficiency of collectors on oxidized zinc minerals. The electric effect of polar groups can improve physical and chemical properties of collectors to strengthen flotation efficiency. Study on the mechanism of the synergetic effects between multipolar groups in depth has significant meanings for accurate control the flotation ability of collectors. Key words：Zinc oxide ore; Multipolar groups; Synergetic effect; Collector 1 引言 随着经济的快速发展，我国对锌精矿的需求量逐年增加，伴随着对易选硫化矿资源的强化和选择性开发，致使其后备资源极其缺乏[1,2]。因而，难选氧化锌矿产资源的高效开发利用迫在眉睫。目前，工业上对于氧化锌矿石最普遍的处理方法是浮选法，而高效浮选捕收剂的设计和筛选是该方法的关键所在。 当捕收剂中存在多个极性基团时，极性基团之间会产生一定的协同作用，这种协同作用可分成两部分。其一是通过多键合作用增加捕收剂的捕收能力和选择性；其二是通过极性基团间的电子效应在分子内实现电子传递，增加或减弱极性基团的极性，从而改变捕收剂的物理化学性质。在前期研究过程中，国内外研究者基于极性基之间的协同效应，成功开发了多种新型、高效的氧化锌矿捕收剂，为提高氧化锌矿物资源的回收利用效率奠定了一定的基础。 2 极性基团间多键合作用 2.1 螯合作用 螯合