以磷酸酯化前处理进行纤维素奈米纤维的制备及其应用.pdf

以磷酸酯化前處理進行纖維素奈米纖維 (CNF)的製備及其應用 以磷酸酯化前處理進行纖維素奈米纖維的製備及其應用 蘇裕昌* Preparation and Application of CNF with Phosphorylation Pretreatment Yu-Chang Su* Summary Japan Oji Paper Holding Corporation had successfully developed a pulp phosphorylation method as a chemical pretreatment for CNF preparation. This article introduced the preparation of CNF by using phosphorylation pretreatment, preparation and characterization and application technology development of the resulting CNF were also discussed. In the phosphating reaction, phosphate groups were introduced to positions of C3 and C6 of glucose unit in surface of a cellulose molecule to substitute hydroxyl groups. The advantages of the phosphorylation pretreatment method for CNF preparation were as follows. First, low energy requirement for CNF preparation. Second, resulting CNF can be reached to 3-4 nm in width and the yield is almost reach to 100%. Third, resulting CNF with high transparency and high viscosity. Keywords: Cel lulose nano fiber(CNF), phosphorylation of pulp , phosphorylated CNF,CNF application 一、緒言 設定做為諸如汽車和飛機的構件的高強度樹脂複合材料、 高氣阻性的包裝材料、化妝品的增粘劑等用途上。此外， 近年環境意識的高騰，循環型資源的木質生物質廣受 由於CNF 片材(Sheet)具有高透明度、尺寸安定性、柔韌性 注目。其中，特別是被高度期待的素材纖維素奈米纖維 (以 等特性 ，而可作為彈性顯示器(Flexible display)的部分構材 下簡稱CNF)的研究開發及應用的拓展，已經在全世界各國 (河崎雅行，2018) 。 家呈現飛躍性的成長。CNF 是纖維素分子鏈三維構造中之 一維經奈米化而仍維持規則性排列的結晶分子束亦可以微 一般，CNF 可以由紙廠大量生產的寬20-30 mm 、長 纖毛(Microfibril)稱之，其寬度約為3-4 nm 、長度約為幾十 度0.5-3 mm 的木材紙漿為原