一种新型变形高温合金的组织与性能分析.docVIP

44 5 Vol.44 No.5 20085 540—546ACTA METALLURGICA SINICA May 2008 pp.540–546 5 : 541 1 M 23C 6 M C M 6C . Haynes , national Inc., USA , Waspaloy , Ti Waspaloy Waspaloy (HaynesInter-1(. , γ′, . , , Mo : 13mm ( 2 . , 10mm –. 0.2mm MTP–1 10%50—60V, , , – , – :50μm, , 13mm . +1010, 2h . 1149 , :1149, +788, 8h , ; 1010 +65% 50mA, ?25—?20. 200kV JEM–2000FX +25% , . , ( 2 γ′ , γ′ 2.1 ; 788 . γ′ , 1 Thermo–Calc 1 [7, 8] , , Thermo–Calc 1. . 2 . 1, γ′+M 23C 6+M C +M 6C; 23, M 23C 6+M C +M 6C, , γ′; M 23C 6+M C +M 6C , 4, M 23C 6; 5 , Thermo–Tech . 1, γ, γ′, M C, M 6C M 23C 6, μσ. γ1354, 1295—1354. , γ′1002, ; μ800, ; M 23C 6916, 1.16%;817σ. M C M 6C 1080—1290800—1200 M C, M 23C 6+M C +M 6C , 0.2% 2.15%. 1Waspaloy Table 1Chemical compositions of Waspaloy alloy and the tested alloy (massfraction, % Alloy Waspaloy Tested alloy Cr 19.019.5 Co 13.510.0 Mo 4.38.5 Al 1.51.5 Ti 3.02.1 C 0.080.06 Fe 2.01.5 Mn 0.10.3 Si 0.150.15 B 0.0060.005 Zr 0.05– Ni Bal. Bal. 2 Table 2Solutions and conditions for phase extraction and separation Solution No. 12345 H 2SO 4 Solution and condition 0.5%HNO3+2%C6H 8O 7+H 2O t =5—10t =?10—?5t =?10—?5 Reserved phase γ′+M 23C 6+M C +M 6C M 23C 6+M C +M 6C M 23C 6+M C +M 6C M 23C 6M C , J =0.03A/cm2 3.6%ZnCl2+5%HCl+1%C6H 8O 7+CH 3OH , J =0.05—0.08A/cm2, J =0.05—0.08A/cm2 5%HCl+5%C3H 5(OH3+1%C6H 8O 7+CH 3OH 20%H2O 2+5%H2SO 4+H 2O Heat preservation in boiling water for 1.5h H 2O=1 1(volumeratio, boiling until it smoke 542 44 1 Fig.1Thermodynamically calculated curves of the amount of precipitates in the tested alloy vs temperature , γ , γ′, M 23C 6, M 6C, M C μ . 2.2X , 2 . , ′ γ , γ, M 23C 6, M C M 6C . , M C , 0.163%;M 23C 6 1 , ′ 0.668%;γ2 , . u . a , y t i s n e t n I 20406080100 2d eg . u . a , y t i s n e t n I 20406080100 2 d eg 2 XRD Fig.2XRD analysis results of phases in the tested alloy (aspectrum of γ′phase (bspectra of M 23C 6, M 6C and M C 5 4 % , 3 y t i l i b a b o r 2 P 1 01224364860 Grain size, nm 3γ′ Fig.3Distribution of grain size of