35二恶英的采样及分析方法2015.docVIP

? Source Testing Overview ? Comparison EU, Canada, Japan, S. Korea USA ? Insights for Development of Methodology ? Dynamic Systems Phases of Source Testing Phases of Source Testing Specific Aspects Countries Sampling ? Type of Sampler ? Sampling Time ? Sorbent ? Filter Box Temperature ? Sampling Spikes Sampling ? Type of Sampler ? Sampling Time ? Sorbent ? Filter Temperature ? Sampling Spikes Recovery ? Reagent ? Impinger Sampling ? Type of Sampler ? Sampling Time ? Sorbent ? Filter Temperature ? Sampling Spikes Recovery ? Reagent ? Impinger Analysis ? Sample Preparation ? Sample Analysis Sampling ? Type of Sampler ? Sampling Time ? Sorbent ? Filter Temperature ? Sampling Spikes Recovery ? Reagent ? Impinger Analysis ? Sample Preparation ? Sample Analysis Reporting ? TEQ / Totals ? Detection Limits ? Recoveries Incinerator Type 问题3：中国二噁英排放限值是多少？ Stand Authority Method Guideline MWC MWI, HWI, BIF 30/13 ng Total / dscm Proposed 23 MWC MWI, HWI 0.5 ng TEQ / dscm (1) Environment Canada Province Jurisdictions (accept EPA results) Spl.: EPS-1/RM/2 QA: 1/RM/23 Anal.: 1/RM/19 MWC HWI 0.1 ng TEQ / dscm Each Country Regulatory Agency EN 1948 Part 1: Sampling Part 2: Extr. CU Part 3: Id. Quant. MWC Ministry of Health 0.1 ng TEQ / dscm and Welfare JIS-Z-8808 MWC 0.5 ng TEQ / dscm (Seoul: 0.1 ng) Ministry of Environment APTM 3C29 (1) CCME - Canadian Council of Ministry of Environment guideline. New reg. in preparation for “virtual elimination”. Ontario guideline is 0.1 ng TEQ / dscm. Sampling Sample Recovery Sampling Features FCM Sampler Type FCM FCM CPM FCM FCM DM 1) FCM = Filter Condenser Method (USEPA MM5); 2) CPM = Cooled Probe Method (Sweden, Norway, Germany); 3) DM = Dilution Method (NL, A, D) Nozzle Probe Filter optional Suction Measuring Device Side Stream Condenser Condenser Absorbent Flask Stack Wall Gas sample is cooled to below 20oC. Gaseous and aerosol parts of PCDD/Fs are captured by impingers and/or solid adsorbents. Suction Measuring Device