EPA 9216 POTENTIOMETRIC DETERMINATION OF NITRITE-国外标准规范.pdfVIP

METHOD 9216 POTENTIOMETRIC DETERMINATION OF NITRITE IN AQUEOUS SAMPLES WITH ION-SELECTIVE ELECTRODE SW-846 is not intended to be an analytical training manual. Therefore, method procedures are written based on the assumption that they will be performed by analysts who are formally trained in at least the basic principles of chemical analysis and in the use of the subject technology. In addition, SW-846 methods, with the exception of required method use for the analysis of method-defined parameters, are intended to be guidance methods which contain general information on how to perform an analytical procedure or technique which a laboratory can use as a basic starting point for generating its own detailed Standard Operating Procedure (SOP), either for its own general use or for a specific project application. The performance data included in this method are for guidance purposes only, and are not intended to be and must not be used as absolute QC acceptance criteria for purposes of laboratory accreditation. 1.0 SCOPE AND APPLICATION 1.1 This method can be used for measuring nitrite in drinking water, wastewater, and reagent waters. If this method is used for other types of water samples (i.e., surface water, ground water, etc.), method precision and accuracy must be demonstrated for each matrix type. 1.2 Ion selective electrodes (ISEs) must be used carefully and results must be interpreted cautiously, since an ISE may be affected by numerous analytical interferences which may either increase or decrease the apparent analyte concentration, or which may damage the ISE. Effects of most interferences can be minimized or eliminated by adding appropriate chemical reagents to the sample. Obtaining the most accurate results, therefore, requires some knowledge of the sample composition. NOTE: ISE manufacturers usually in