绿色化学中的新催化方法.pptVIP

Catalytic Oxidation CH3CHCH2 + HOCl CH3CH(OH)CH2Cl PO + CaCl2 + H2O Ca(OH)2 Chlorohydrin Route Stoichiometric amounts of salt waste AE=31％ Direct Oxidation Still not viable but Enichem are getting close CH3CH=CH2 + H2O2 PO+H2O Ti Silicate Cost? AE=76％ BP Amoco - Cr/Ag cat - 50% sel at 15% conv Olin - Mo cat - 60% sel at 12 % conv Future Possibilities AE=100％ * /pdf/gcn/atomeff.ppt eg: Propylene Oxide - The Search For The Ideal Catalyst ＊ Hydrogen Peroxide Anthraquinone process * Bing Zhou. US Patent 6,168,775B1 Direct Catalytic Hydrogen Peroxide Production ＊ H2 + O2 process 2007 * J.H. Clark. Chinese Journal of Nature (22): 1-6 2000 eg: Maleic Anhydride Production Routes + 4 . 5 O 2 V 2 O 5 O O O + 2 C O 2 + 2 H 2 O Benzene Oxidation AE=44.1% C%=67% H%=33% O%=33% + 3 O 2 V 2 O 5 O O O + 3 H 2 O Butene Oxidation AE=64.5% C%=100% H%=25% O%=50% O + 3 . 5 O 2 O O V 2 O 5 + 4 H 2 O Butane Oxidation AE=61.3% C%=100% H%=20% O%=43% The Triple Bottom Line ＊ * * * * * * * * * * * * * * * * S. He (songbohe@) Seminar I New Catalytic Technologies in Green Chemistry S. He (songbohe@) Seminar I New Catalytic Technologies in Green Chemistry Seminar I * 绿色化学中的新催化方法 研究生：何松波 导 师：孙承林 研究员 New Catalytic Technologies in Green Chemistry 论文题目：《长链烷烃脱氢催化剂和工艺的研究》 绿色化学中的新催化方法 Contents About “Green Chemistry” Role of “Green Catalysts” Some new “Green Catalytic Technologies” Some Conclusions About “Green Chemistry” ** /greenchemistry/ ** 1Definition*： Green Chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. * Paul T. Anastas 著李朝军 译 《绿色化学理论与应用》科学出版社 2002 2 Development ： 1990 Pollution Prevention Act of 1990 1991 ACS & EPA 1995 The Presiental Green Chemistry Challenge “Atom Economy” and “E-Factor” Reaction Yield and Sel