二维金属膜中量子阱态对化学反应性质的调控.pptVIP

* * * 二维金属薄膜中量子阱态对化学反应活性的调控 内容 介绍 量子阱态 (QWS) 概述 量子阱态对反应活性调控的可能性和实例 量子阱态对反应活性调控的可能性 铅薄膜中量子阱态对吸附活性的调控 (O2 ,Fe, CoPc) 铜薄膜中量子阱态对CO吸附的调控 镁薄膜中量子阱态对氧化活性的调控 结论和展望 λF is Fermi electron wavelength related to Free Electron Density (FED) In in the solid. λF = 2π/ kF KF = (3π2 N/V)1/3 N/V is free electron concerntration [2] Compared to λF How small? 量子阱态（QWS) Confinement of electrons in small structures such as a thin Film results in discrete quantum well states [1] KF Cm-1 εF eV λF nm Cu 1.35x108 7.0 0.46 nm Ag 1.19x108 5.5 0.52 nm Au 1.20x108 5.5 0.52 nm Metal: FED = 1022 -1023 cm-3 λF ~ 1 nm; Semiconductor: FED = 1017 cm-3 λF ~ 50 nm introduction [1] T. –C Chiang, Surf. Sci. Rep. 39 (2000) 184 [2] C. Kittle, Introduction to solid state Physics,3rd ,203 T. –C Chiang, Surf. Sci. Rep. 39 (2000) 184 Quantum well state introduction Potential Well model for Quantum Well State ?n＝2L / n L E introduction Particle in a box model 1D finite potential well 1D infinite potential well Standing wave Ag/Au(111) QWS in Ag films T. Miller et. al, PRL, 61(1988) 1404 T. –C Chiang, Surf. Sci. Rep. 39 (2000) 184 introduction QWS in Pb films Si Valence Band Fermi level 0.46eV Conduction band Lead film P band Band Gap 1.2eV confinement gap ( 0.46 eV ) Pb Si（111） Vacuum interface Pb thin films on Si(111)-7x7 Yang guo and Qi-Kun Xue, Science, 306 (2004) 1915 M Milun et al, Rep. Prog. Phys. 65 (2002) 99 introduction Superconductivity Modulated by Quantum Size Effects Yang guo and Qi-Kun Xue, Science, 306 (2004) 1915 QWS effect on Physics Gas adsorption on Solid Surface R E 0 Possibility 量子阱态对表面吸附的影响 E E 分子轨道 N 层 M 层 It is possible Pb Si 量子阱态对表面吸附的影响 Case 1 Chemical Reactivity-Case 1 500nm x 500nm Chemical adsorption modulated by QSE O2 (~60L @ LN2) Oxygen@ Pb film 10ML 11ML 12ML 10ML 10ML 11ML 12ML Chemical Reactivity-Case 1 Ma et al, PNAS, 104 (2007) 9204 L. Ma, Q. K. Xue et al, PRL, 97 (2006) 266102