《精细化学品化学(双语)》试题答案及评分标准(B).docVIP

《精细化学品化学（双语）》试题答案及评分标准（B） 1. Please define following words briefly（24/100） 1）Pesticide A pesticide is any substance or mixture of substances intended for preventing, destroying, repelling, or mitigating any pest. Pests can be insects, mice and other animals, unwanted plants (weeds), fungi, or microorganisms like bacteria and viruses. 2）Azo dyes Any of a large class of synthetic organic compounds, dyes containing two nitrogen atoms joined by a double bond in the form -N=N- as part of their molecular structure. 3）Coupling agent A substance that can react with both reinforcement and matrix components of a composite material to form a binding link at their interface. 4）Green chemistry The term green chemistry is defined as: The invention, design and application of chemical products and processes to reduce or to eliminate the use and generation of hazardous substances. 5）Surfactant A shortened form of surface-active agent, a surfactant is a chemical that stabilizes mixtures of oil and water by reducing the surface tension at the interface between the oil and water molecules. 6）Amino Resins Amino resins are those polymers prepared by reaction of either urea or melamine with formaldehyde. 2. Please give the structures of the compounds listed below（18 /100） Initiator: BPO Plasticizer: DOP Herbicide: chloraulfuron Initiator: AIBN Spice: vanillin Azo dyes: methyl orange 3. Please figure out the synthetic routes for making the following dye compounds (could have multi-steps) (12/100) 4. Please name the structure of the pesticide printed below and give the synthetic route towards this pesticide? (12/100) Name: chlorfluazuron 5. Calculating:（12/100） An alkyd resin formulation is as follows: Linseed oil:100.00 g; Lithium hydroxide(catalyst):0.400 g; Glycerol(98%):43.00 g; Phthalic anhydride(99.5%):74.50 g (Sublimation loss about 2%). Please calculate the Mglycerol =92 g/mol，n(glycerol)：43× Moles of hydroxyl group in glyce