充放电循环及比容量图.ppt

Specific capacity 电池的容量是指在一定的放电条件下电池所 给出的电量,常用C表示,单位为Ah。 分理论容量、实际容量和额定容量。 按法拉第定律去理论容量为: Co=26.8mn/M=m/a m:活性物质完全反应的质量 M:该物质摩尔质量 n:化合价变化 q:电化学当量 实际容量C:恒流放电时C=t 恒阻放电时C=lt=1/RVt=1/RV平t 利用率k=CCo R为放电电阻,V为平均放电时的平均电压,t为放电时间 单位质量或单位体积的电池所给出的容量 C′=C/m Cy=C/ 通过比容量计算嵌入锂离子的摩尔数: C=200mAh/g=200*3.6库伦/g Mxo=2410966 ZFO的摩尔数,n=1/M mollO通过的电荷量Q=200*3.61=200*36+Mzo库伦 生成或溶解1mol物质所需要电量为F(法拉第常数)=1.60*10-*6.02*103=96485C/mol 所以 lmolzFo嵌入的Li=QF=200*36+241.0966.6010-9*602*102)=1.8mOl Chem Comm 2,5 5 th 10u 20 th 20 30 th 815 10 05 0.0 40060080010001200 eciC Capa One-pot synthesis of ZnFe204/C hollow spheres as superior anode materials for lithium ion batteries Fig. 3a and b illustrate the discharge charge profiles and cling performance of the Zn Fe,02C hollow spheres a anode materials for LIBs, respectively. It can be seen that southe Zn Fe 204/ C hollow spheres exhibit a high initial discharge specific capacity of 1254 mAh g. A reversible specific capacity of 841 mAh g can be obtained after 30 cycles at constant current density of 65 mA g. As shown in Fig 3a, the voltage profile of ZnFe,02 C between 0.01 V and 3.0Vin o 200 400 60 800 100 120 the first discharge has two small voltage plateaus(0.90 and 0.5V and a more obvious one(about 0.85 V). The first discharge curve starting from the open circuit voltage(<2.5 v)shows a continuous voltage decrease to o90 v with an intercalation reaction involving about 0.3 mol lithium ions. The following 8.:5:11:m:1811 up to a consumption of 1.0 mol of Li. The capacity of reaction results in a voltage plateau at 0.90 V, which extend 150 mAh g in this region corresponds to a consumption of 301.3 mol of Li per mole of ZnFe, O4, based on the weight of the active material and formula weight of the ZnFe20 This can be ascribed to the formation of Li ZnFe, 04. The voltage ther decreased to 0.85 v and the second plateau was observed xtending up to a consumption of 6.0 mol of Li. This can be attributed to the reduction of Fe, Fe- and zn and Zn"as well as to