反渗透_纳滤过程的物理化学研究_多孔膜的溶质脱除率方程和膜渗透通量方程.pdf

　57 　3 　 　　　　　　　　　　　　　 　　　　Vol.57　No.3 　 2006 3 　 　Journal　of　Chemical　Industry　and　Engineering　(China) 　 　March　2006 、 (Ⅰ) 姬朝青, 陈　浩 (, 313000) :;;; : Q 028.8　　　　　　:A :0438- 1157 (2006) 03 - 0601 - 06 Physical chemistry study on RO and NFprocess (Ⅰ) Equations of solute rejection and solution permeation flux on porous membrane JI Chaoqing, CHENHao (Zhej iang Stone Environment Engineering Co. L td, H uz hou 313000, Zhej iang, China) Abstract: he equations of solute rejection and solution permeation flux of mult-i solute solution on porous membrane were derived on the basis of the adsorption-diffusion model. he physical significance of parameters in the equations was discussed. From the equations of solute rejection and solution permeation flux on porous membrane, the following conclusions were reached:when the solvent was adsorbed preferentially on the membrane surface, solute rejection could decrease as the membrane porosity increased;when the solute was adsorbed preferentially on the membrane surface, three curves of solute rejection vs. membrane porosity were obtained;solute rejection could decrease as membrane porous rate increased;a minimum value was shown on the curve of solute rejection vs. membrane porous rate;a min value and a max value was shown on the curve of solute rejection vs. membrane porosity. he solution permeation coefficient depended on the solute diffusion coefficient and diffusion selectivity of solute with solvent in the membrane phase. Membrane fouling was caused by the fact that the solute was adsorbed preferentially on the membrane surface, leading to increased membrane surface resistan