（降重）锰基复合电极的制备及其电化学性能研究.docx

经典专科、本科、硕博、研究生、期刊毕业论文 仅供参考 精心整理 仅供参考 勿用作商业用途 锰基复合电极的制备及其电化学性能研究 摘要：使用水热法在160 ℃下制备二氧化锰的纳米棒状结构。只利用高锰酸钾和乙酸乙酯两种原料，采用溶剂热法制得二氧化锰纳米片材料，分别利用扫描电镜（SEM）、X射线衍射（XRD）、电池充放电及循环测试等测试手段对材料的形貌、结构做出表征。运用恒电流充放电的方法对材料的电化学性能进行测试。 在空气中和在氩气中500℃温度下烧，400 mA g-1电流密度下的循环性能测试曲线。在空气中500℃烧时，其电极的储锂性能最好。 (2)在以PF127为表面活性剂的实验中，水和乙醇的比例变化会影响锰的价态和形貌，进而影响材料的储锂性能。只有水和乙醇含量分别为30ml和5ml时，电极方能达到最佳的储锂性能。 （3）从放电容量方面来看，电流密度为600 mA g-1中，各比例的长循环性能在30 ml水和5 ml乙醇为溶液时所制得的锰的氧化物在前200圈具有最高的放电容量，但是在140圈以后，电池的放电容量逐渐减低，这可能是在长循环过程中，材料出现粉化情况造成的。 （4）高锰酸钾水溶液和乙酸乙酯混合，在85℃温度下冷凝回流所制得的材料，400 mA g-1电流密度下的循环性能测试曲线可以看出，在反应了22小时后，但电极容量逐渐降低，所以考虑进行硫化处理。硫化处理后可以看出电极容量明显提升，初始库伦效率也明显提升，但仍然未解决容量随着循环次数的增加而减小的问题。 关键词：锂电池负极材料；钠电池负极材料；电化学性能；纳米棒；纳米片 Abstract: The nanorod-like structure of manganese dioxide was prepared by hydrothermal method at 160 °C. Using only potassium permanganate and ethyl acetate as raw materials, MnO2 nanosheets were prepared by solvothermal method. The scanning electron microscopy (SEM), X-ray diffraction (XRD), battery charge and discharge, and cyclic testing were used. Characterize the topography and structure of the material. The electrochemical properties of the material were tested using a galvanostatic charge-discharge method. (1) Cycle performance test curves at a current density of 400 mA g-1 in air and at a temperature of 500°C in argon. When burned in air at 500°C, the electrode has the best lithium storage performance. (2) In the experiment of using PF127 as a surfactant, the change of the ratio of water and ethanol will affect the valence and morphology of manganese, and then affect the lithium storage performance of the material. Only when the water and ethanol contents were 30 ml and 5 ml, respectively, the electrode could achieve the best lithium storage performance. (3) From the discharge capacity point of view, the current density is 600 mA g-1, and the long-cycle performance of each ratio has the highest discharge in the first 200 laps of the oxides of manganese produced in a solution of 30 ml of wat