有机化学PPT课件教案-Chapter5Stereochemistry立体化学.pdf

Stereochemistry 第五章 立体化学 Organic Chemistry A (1) By Prof. Li Yan-Mei Tsinghua University Content Content Content 5.1 Introduction 5.1 Introduction 5.2 Molecule with one asymmetric carbon 5.2 Molecule with one asymmetric carbon 5.3 Molecule with two asymmetric carbon 5.3 Molecule with two asymmetric carbon 5.4 Molecule with more than two asymmetric 5.4 Molecule with more than two asymmetric carbon carbon 5.5 Cyclic compound 5.5 Cyclic compound 5.6 Other chiral molecules 5.6 Other chiral molecules 5.7 Measure of polarity and reslution of racemic 5.7 Measure of polarity and reslution of racemic compounds compounds 5.1 Introduction 5.1 Introduction 5.1.1 Chirality 5.1.1 Chirality Nicol Plane-polarized light 平面偏振光（偏振光） Non-chiral compounds, Nicol Light source like water 该化合物“无旋光性” “无光学活性” 物质的旋光性：物质使偏振光振动平 偏转角 面发生旋转的性质 旋光度 Chiral compounds, Nicol Light source like lactic acid 该化合物具有“旋光性” 为“旋光物质”或“光活性物质” Specific rotation 比旋光度 α：旋光度 [