一种有机线性光学材料性测量.docVIP

一种有机线性光学材料性测量 摘 要 光致折射率变化效应简称光折变效应，然而光信息处理的最基本手段就是利用光折变效应。应用于各种领域，例如光放大、空间调制器、全光学时间积分器、光振荡、光学记忆、图像存储与复原、图像相减相加和反演、图像相关和卷积。在许多光折变晶体中我们可以观察到光散射现象。但有机材料中比较少见，不过通过实验我们发现，有机材料被溶解时，可以观察到散焦现象。 我们在实验中采用的有机溶剂为，有机溶质为， ，我们配置了不同质量百分比的溶液，用532nm的激光器通过凸透镜聚焦照射溶液，我们发现部分样品出现了自散焦现象其中B，C没有自散焦现象。D，E，F有自散焦现象。当外挂基团处于对称状态时没有自散焦现象，而外挂基团为非对称性时有自散焦现象。我们认为有机材料在受到激光的作用后，材料分子的极性发生了变化，进而产生空间电荷场，这些空间电荷场会让激光束产生自散焦现象，通过对比试验自散焦现象与溶剂无关。空间电荷场的强弱随激光强度的变化而改变。我们自制了一个电路用于观察空间电荷场的电荷分布，得出了两个结论空间电荷场与热效应无关，激光束的偏振态对空间电荷场的强弱没有影响。 关键词：自散焦 空间电荷场 光折变效应 Z扫描 PAGE PAGE 1 Abstract Photorefractive effect is short for light induced refractive change effect.Photorefractive effect has become the basic means of optical information processing,applicating for optical amplifier, optical oscillation, optical memory, image storage and recovery, spatial modulator, all-optical time integrator, image subtraction additive and inversion, image correlation and convolution, and many other fields.People observed light scattering phenomenon in a lot of photorefractive crystal.Through the experimental observation we found that the organic material which is dissolved in organic solvent, defocusing phenomena can be observed. We chose N,N-Dimethylformamide（DMF）as the solvent and 4,4-Biphenol(B)，4-phenylphenol(C)，2-amino-4-phenylphenol(D)，4-hydroxy-4-biphenylcarbonitrile(E)，2-(4-hydroxypheny)-5-pyrimidinol(F)as the solute.we configured different quality percentage for solution.By using the laser of 532 nm,through the lens focuses light,radiated the solution,we found the following conclusion: B, C samples does not have the defocusing phenomenon;D, E, F, samples have the defocusing phenomenon;These samples are of the basical chemical structure of hydroquinone (A), when the external groups are symmetrical without the defocusing phenomenon, but external groups are asymmetryhave with the defocusing.We believe that the organic material under the effect of the laser, polarity of material molecules, changed,producing space charge fie