壳聚糖季氨化聚乙烯醇离子交换膜制备表征.docxVIP

壳聚糖/季氨化聚乙烯醇离子交换膜制备表征 孟枫舒，张宏翔，陈乾，庄佳暖，石华峰，孙玉俊，江献财 *\ (福州大学，石油化工学院，福建 福州350116 ) 指导教师：江献财职称：副教授 摘要：采用氯化铝水溶液为壳聚糖 (CS)的溶剂，通过季氨化改性得到季氨化的 PVA (QPVA),并通过溶液复合制备得到了 QPVA/CSM合薄膜，并研究了 QPVA/C晅合薄膜作为碱性燃料电池隔膜的性能。通过傅里叶变换红外光谱、 X射线衍射分析 和力学性能测试研究氯化铝和甘油对 QPVA/CS复合薄膜的性能的影响。通过吸水率研究了 QPVA/CSM合薄膜的吸水性能， 并对复合薄膜的离子传导率进行了测定。研究结果表明，同时加入氯化铝和甘油改性时，制备的 QPVA/CS复合薄膜的性能 较好，其拉伸强度为 23 ( + 0.67) MPa，断裂伸长率为 235 ( + 2.85)%，离子传导率为 2.028 X 10-2 S cm-1。 关键词：壳聚糖，聚乙烯醇，阴离子交换膜，六水合氯化铝，甘油 Preparation and characterization of quaternized poly(vinyl alcohol)/chitosancomposite anion exchange membrane Fengshu Meng, Hongxiang Zhang, Qian Chen, Jiayuan Zhuang, Huafeng Shi, Yujun Sun, Xiancai Jiang (School of chemical engineering, Fuzhou University, Fuzhou, Fujian 350116, China ) Abstract: In this paper AlCl 3 6H2O aqueous solution was used as the solvent for chitosan, and quaternized poly(vinyl alcohol)/CS (QPVA/CS) membrane was prepared by solution casting. The effect of AlCl 3 6H2O on the the hydrogen bonding interaction, crystalline properties and mechanical properties was studied by fourier transformed infrared spectra, X-ray diffraction measurement and tensile testing, respectively. The ion conductivity of QPV A/CS membrane was studied by AC impedance method. The results showed that both AlCl 3 6H 2O and glycerol could form interaction with QPV A/CS. With the addition of AlCl 3 6H 2O and glycerol, the crystallinity of QPVA/CS membrane decreased and the flexibility of QPVA/CS membrane increased. With the addition of AlCl 3 6H2O and glycerol, the elongation at break of QPVA/CS could reach to 235 + 2.85% and the ion conductivity could reach to 2.028 10-2 S cm-1. The results of this paper provided a new way for the preparation of high performance QPV A/CS composite anion exchange membrane. Keywords: chitosan, poly(vinyl alcohol), anion exchange membrane, AlCl3 6H2O, glycerol 燃料电池隔膜是燃料电池中的关键部件 ［1］。近年来通过环境友好、成本低廉和电导率高的高分子膜制 备燃料电池隔膜已成为研究趋势。壳聚糖是一种重要的天然高分子材料，其成膜工艺简单，且制备的薄膜 具有好的综合性能， 使得cs在燃料电池隔膜的制备中具有好的应用前景 ［2］。壳聚糖作为单一材料使用时往