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polymers for advanced lithium batteries(劳伦斯伯克利国家实验室材料2011).docx

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Polymers For Advanced Lithium Batteries Nitash P. Balsara Lawrence Berkeley National Lab May 12, 2011 Project ID # ES088 This presentation does not contain any proprietary, confidential, or otherwise restricted information Overview Timeline Barriers ? FY08 ? Energy density ? FY11 ? Safety ? 65% ? Low cycle life Budget FY10 funding: 390 K FY 11 funding: 550 K No contractors Partners Lead: LBNL 2 Milestones Month-Year Milestone Mar-11 Electrochemical characterization of block copolymer electrolytes. Partially accomplished. June-11 Synthesis of a binder that conducts electrons and ions. Accomplished Sept-11 Synthesis of nanoporous block copolymer separators. Accomplished. All go decisions. No show stoppers. Objective Current lithium batteries use a polymeric binder (inactive glue in cathode) and a polymeric separator (expensive inactive polyolefin with pores) . Objective: Comprehensive overhaul of the way polymers are used in lithium batteries Specific Objectives: Characterization of dry nanostructured polymeric separators for stabilizing the lithium metal anode (95% complete). Synthesis and characterization of a polymeric binder that conducts both ions and electrons (50% complete). Synthesis and characterization of templated nanoporous separators (50% complete). Approach Synthesize block copolymers Study morphology and ion and electron transport Build and test full cells Nanostructured solid Electron- and ion- Nanoporous separator electrolyte conducting binder H2 H2 O C C y H s-Bu CH x C H2 Salt, LiTFSI F F F O O F F S N- S F O Li+ O Technical Accomplishments Nanostructured solid electrolyte soft phase conducts ions hard phase prevents dendrite formation Symmetric lithium-polymer-lithium cell experiments Technical Accomplishments Nanostructured solid electrolyte Measurement of diffusion coefficient by restricted diffusion. Technical Accomplishments Nanostructured solid electrolyte Signal resolved over orders of magnitude. Technical Accomplishments Nanostructure