高等有机化学：Chapter 4 Conformational, Steric, and Stereoelectronic Effects.pdfVIP

Chapter 4 Conformational, Steric, and Stereoelectronic Effects 1 Factors connected with molecular geometry contributing to total energy non-bonded repulsion ring strain in cyclic systems destabilization resulting from distortion of bond lengths or bond angles from optimal values conformations: various shapes that a given molecule can attain by rotation about single bonds conformers or rotamers (interconvertible, nonseparable) If not interconvertible configur