细菌纤维素的改性及其对重金属离子吸附性能研究—对水中铅、铜的去除作用研究.docxVIP

细菌纤维素的改性及其对重金属离子吸附性能研究——对水中铅、铜的去除作用研究 摘 要 如今可为水处理领域所利用的吸附剂种类越来越多，对于吸附剂的性能要求也因环境问题的恶化变得越来越高。其中以高分子化合物作为材料的吸附剂因其良好的降解性受到不少青睐。采用超微网型纳米纤维结构和高比例表面积纤维质羟丙基甲基纤维素作为细菌纤维素,该纤维素不管是结构还是物理性质都满足本论文所需的吸附性能。四氧化三铁是磁性氧化物，它在水中即使形成超极细微的颗粒，也可以用磁铁将水中的四氧化三铁分离出来，所以可以作为良好的载体。本论文以氧化铁、氢氧化纳、硫酸亚铁为原料，用共沉淀法制准备四氧化三铁。利用原位合成法将制备出来的四氧化三铁与细菌纤维素结合，生成本论文所需要的磁性纤维素，进而探究其应用问题，对水中重金属铜、铅的吸附性能进行探究。 通过吸附实验和分析实验结果，主要得出以下结论： （1）所选吸附剂具备理想吸附剂所应有的一大特性。采用的超微网型纳米纤维结构和高比例表面积纤维质羟丙基甲基纤维素作为细菌纤维素,很好地跟磁性材料四氧化三铁配合产生良好的吸附效果。 (2) 本论文的吸附实验之所以采用正交法，是为了充分考虑PH值、吸附剂吸附时间(min)以及吸附剂用量(g)这三个因素，从而能够在数十个实验当中得出最佳吸附效果组合。对于吸附实验，pH控制在6-7比较适合重金属离子吸附，在吸附过程中，重金属吸附到一定程度后，吸附容量趋于饱和，吸附效率也趋于平衡。 关键词：共沉淀法、吸附、重金属、磁性纤维素、吸附性能 Modification of bacterial cellulose and its adsorption of heavy metal ions - removal of lead and copper in water Abstract At present, more and more adsorbents which can be used in the field of purification of sewage spring up like mushrooms, and the performance requirements of adsorbents are becoming higher and higher because of the deterioration of environmental problems. Among them, the adsorbent with polymer as the material is favored for its good degradation. The nanofiber structure of ultra-fine mesh and high proportion of hydroxypropylmethylcellulose with surface area were used as bacterial cellulose.Fortunately, The structure and physical properties of the cellulose accord with the adsorption requirements of this paper. Fe3O4 is a kind of magnetic oxide. It can be used as a good carrier to separate Fe3O4 from water even if it forms super fine particles. In this paper, ferric oxide, sodium hydroxide and ferrous sulfate were used as raw materials to prepare ferric oxide by coprecipitation.. In this paper, the magnetic cellulose was produced by combining the prepared Fe3O4 with bacterial cellulose by in-situ synthesis, and then the application of the magnetic cellulose was explored.. Through experiment of the adsorption and analyzed the experimental results, the main conclusions are as follows: (1) The