臭氧催化氧化技术在煤化工含盐废水深度处理中的应用.pdf

第43卷第2期 煤炭与化工 Vol.43 No.2 2020年2月 Coal and Chemical Industry Feb. 2020 化工工艺与工程 臭氧催化氧化技术在煤化工含盐废水深度处理中的应用 郭剑浩 ，金政伟 ，杨 帅 ，任 斌 ，李蕊宁 ，汪丹丹 （国家能源投资集团神宁煤炭化学工业技术研究院 ，宁夏银川750411） 摘要 ：为响应政府 “工业废水零排放”政策 ，煤化工水处理领域通常采用臭氧催化氧化技 术对含盐废水进行深度处理 ，使出水COD满足后端工艺单元 ，如膜处理单元 、蒸发结晶单元 的进水要求 ，从而保证装置的整体稳定运行 。着重介绍了臭氧催化氧化降解有机物的反应机 理 、该技术的分类及不同技术的反应方式 、当前研究水平下制备催化剂的常用材料 ，并阐述 了不同材料作催化剂时的优劣 ，总结了对氧化过程影响较大的六类因素 ，探讨了该技术的发 展方向。 关键词 ：含盐废水 ；臭氧 ；催化氧化 ；影响因素 中图分类号 ：X784 文献标识码 ：A 文章编号 ：2095-5979 （ 2020 ） 02-0136-04 Application catalytic ozonation technolog in the advanced treatment of coal-chemical industr brine wastewater Guo Jianhao, Jin Zhengwei, Yang Shuai, Ren Bin, Li Ruining, Wang Dandan, Jin Zhengwei (Shenning coal chemical Industing Technology Institute China Energy Investment Group, Yinchuan 750411, China) Abstract: In response to the policy of zero discharge of industrial wastewater, the catalytic ozonation technology is usually used in the advanced treatment of brine wastewater in the coal-chemical industry to make the effluent COD meet the requirements of following processes such as the membrane craft and evaporation crystallization to ensure the overall stable operation of the equipment. The reactive mechanism of the organism degrading by the catalytic ozonation, the classification of this technology and reactive ways o£ each, the materials commonly used to prepare the catalyst under current research level were mainly introduced.The merits and demerits of different materials to prepare the catalyst; were elaborated. Six major factors in the oxidation process were summaried. The prospect of the catalytic ozonation technology was explored. Key