差热扫描分析仪培训教程.pptxVIP

第1页/共121页差热扫描分析仪培训教程第2页/共121页DSC: TerminologyAmorphous Phase - The portion of material whose molecules are randomly oriented in space. Liquids and glassy or rubbery solids. Thermosets and some thermoplastics.Crystalline Phase - The portion of material whose molecules are regularly arranged into well defined structures consisting of repeat units. Very few polymers are 100% crystalline.Semi-crystalline Polymers - Polymers whose solid phases are partially amorphous and partially crystalline. Most common thermoplastics are semi-crystalline.Melting - The endothermic transition upon heating from a crystalline solid to the liquid state. This process is also called fusion. The melt is another term for the polymer liquid phase.Crystallization - The exothermic transition upon cooling from liquid to crystalline solid. Crystallization is a function of time and temperature.Cold Crystallization - The exothermic transition upon heating from the amorphous rubbery state to the crystalline state. This only occurs in semi-crystalline polymers that have been quenched (very rapidly cooled from the melt) into a highly amorphous state.Enthalpy of Melting/Crystallization - The heat energy required for melting or released upon crystallization. This is calculated by integrating the area of the DSC peak on a time basis.第3页/共121页TA Instruments DSC’sDSC 2010DSC 2910DSC 2920第4页/共121页Q系列? DSCQ2000 是顶级的带有多种可选配置的研究级DSCQ200 是具有扩展功能的研究级DSCQ20 是基本型 DSC第5页/共121页DSC Q20P & DSC Q2000 with Pressure Cell第6页/共121页DSC 光量热附件第7页/共121页SDT Q600SDT Q600 同步 DSC-TGA: 同时测量热流和重量变化信号第8页/共121页DSC: 典型 DSC 转变 氧化 或分解热流 -> 放热熔化玻璃化转变交联 (固化)结晶温度第9页/共121页Understanding DSC SignalsHeat FlowRelative Heat Flow: measured by all DSCs except TA Q2000. The absolute value of the signal is not relevant, only absolute changes are used.Absolute Heat Flow: used by Q2000. Dividing the signal by the measured heating rate converts the heat flow signal into a heat capacity signal第10页/共121页From desktop, double-click on Q Series