过渡金属评论.pdfVIP

Transition Metals: Review II 1. Write down configurations for the following metals: a. Ni b. Zr c. Cd2+ d. Ru3+ e. Mo4+ 2. Define each of the following a. Ligand b. Chelate c. Bidentate d. Complex ion 3. What must a ligand have in order to bond to a metal? 4. What do we mean when we say that a bond is a coordinate bond? 5. Name the following coordination compounds, and the complex ions: a) (Co(NH ) )Cl 3 6 2 b) K (PtCl ) 2 4 c) Ru(NH ) Cl2+ 3 5 d) Fe(CN)64- 6. Why do transition metal ions often have several oxidation states, whil eother metals generally have one? Describe the um oxidation states observed along the series ScZn, identifying the element with the highest oxidation state and give the value of this state. What is the most common oxidation state of the elements CoZn? 7. What is meant by a transition element? Summarize, with examples, the dist tive properties of transition elements and show how they are related to the electronic structure of these elements. 8. This questions concerns the d-block elements ScZn a. Describe the general electronic configuration of these elements and the exceptional configurations of chromium and copper b. Describe the bonding in these elements. Use a bonding model to account for the general rease in melting points from Sc (1540°C) to Cr (1857°C), followed by a general decrease to Cu (1083) and Zn (420°C). c. Ex in why the compounds of these elements are often coloured. d. Iron is an important d-blo