不饱和基笼型倍半硅氧烷改性不饱和聚酯树脂的中期报告.docxVIP

不饱和基笼型倍半硅氧烷改性不饱和聚酯树脂的中期报告 摘要： 本文报道了一种不饱和基笼型倍半硅氧烷改性不饱和聚酯树脂的合成及其性能研究。通过改性反应将笼型倍半硅氧烷引入不饱和聚酯中，得到了具有较好机械性能和耐温性能的新型聚合物材料。改性反应条件的优化以及不同含量的笼型倍半硅氧烷对其性能的影响进行了研究。结果表明，当笼型倍半硅氧烷含量为5%时，合成的不饱和基笼型倍半硅氧烷改性不饱和聚酯树脂具有最佳性能，其拉伸强度为75MPa，断裂伸长率为6.7%，热分解温度为332℃，热稳定性较好。 关键词：不饱和聚酯树脂；笼型倍半硅氧烷；改性反应；性能研究 Introduction: Unsaturated polyester resins are widely used in the fields of coatings, high-strength composite materials, and adhesives due to their excellent mechanical properties, corrosion resistance, and easy processing properties. However, their poor thermal stability limits their practical application. Therefore, it is of great significance to develop high-performance unsaturated polyester resins with excellent thermal stability. Silicon-containing materials have excellent thermal stability and mechanical properties. Cage-type silsesquioxanes are a new type of silicon-containing material with a three-dimensional cage structure composed of Si-O-Si bonds, which can impart excellent mechanical, thermal, and electrical properties to the polymer materials. In this study, we introduced cage-type silsesquioxane into unsaturated polyester resin through modification reaction to obtain a new polymer material with excellent mechanical and thermal properties. Experimental: Materials and equipment: Maleic anhydride, phthalic anhydride, propylene glycol, styrene, hydroquinone, sodium acetate, and other reagents were purchased from Beijing Chemical Works. The cage-type silsesquioxane (Octakis [3-(2-propenyl) oxypropyl ] cage silsesquioxane) was purchased from Alfa Aesar. The equipment used included a four-necked round-bottomed flask, a thermometer, a condenser, a magnetic stirrer, etc. Synthesis of unsaturated polyester resin: The unsaturated polyester resin was synthesized by the esterification reaction of maleic anhydride, phthalic anhydride, and propylene glycol. The synthesis process involved the following steps: 1. Weigh 81.75 g of phthalic anhydride, 57.25 g of maleic anhydride, and 132 g of propylene