储能电池及技术应用.pptxVIP

第九届中国国际储能大会 2019.4.24-26 杭州 中国 退役锂离子电池回收与资源化技术 Recycling ofspent lithium-ion batteries: a review ofcurrent processes andtechnologies 李 丽 ， 吴 锋* 北京理工大学 E-mail:lily863@bit.edu.cn; wufeng863@bit.edu.cn 1 第九届中国国际储能大会2019.4.24-26 Categories Materials Properties Potential environmental pollution Cathode material LiCoO2/LiMn2O4/LiNiO2 /LiNiCoMnO2 Reacts with water, acids, reducing agents or strong oxidizing agents (hydrogen peroxide, chlorate, etc.) to produce harmful metal oxides. Heavy metal pollution raises the environmental pH Anode material Carbon material / graphite, lithium intercalation in case of fire or high temperature, dust can explode and react with strong acid and strong alkali to produce gases such as CO and CO2. The CO and solid dust particles produced by the combustion of the anode material contaminate the air. Electrolyte LiPF6/LiBF4/LiAsF6 It is highly corrosive and can produce HF when exposed to water, and can be oxidized to produce toxic substances such as P2O5 , Li2O, B2O3 Fluorine pollution changes the pH of the environment, and the toxic gas generated pollutes the air and stimulates the human body through the skin and breathing. Electrolyte solvent Ethylene carbonate / Propylene carbonate / Dimethyl carbonate The hydrolyzate produces aldehydes and acids, which can produce CO, CO2 , etc. Organic matter such as aldehydes, ketones, and methanol Separator PP/PE Combustion can produce CO, aldehyde, etc. Organic pollution Binder PVDF 、VDF 、EPD It can react with fluorine, fuming sulfuric acid, strong alkali, alkali metal, and decompose by heat to produce HF. Thermal decomposition produces HF and fluorine pollution 第九届中国国际储能大会2019.4.24-26 第九届中国国际储能大会2019.4.24-26 第九届中国国际储能大会2019.4.24-26 第九届中国国际储能大会2019.4.24-26 第九届中国国际储能大会2019.4.24-26 Diagrammatic sketch of reaction mechanism Possible structures