两步法催化桐油制备生物柴油工艺及动力学研究的开题报告.docxVIP

两步法催化桐油制备生物柴油工艺及动力学研究的开题报告 摘要 本文研究采用两步法催化桐油制备生物柴油工艺及动力学。首先，采用硫酸铬钾催化剂对桐油进行酯化反应生成桐油甲酯；然后，采用氢氧化钾催化剂对桐油甲酯进行酯交换反应生成生物柴油。在此基础上，对反应条件和动力学进行了研究，结果表明： （1）催化剂的种类和催化剂的用量对反应的影响较大，硫酸铬钾和氢氧化钾分别最适宜使用0.5%和0.8%的催化剂用量。 （2）温度和反应时间对反应的影响也较大，最适宜的反应温度为60℃，反应时间为4小时。 （3）在最优反应条件下，反应速率符合一级反应动力学规律，反应动力学参数为k=0.03568，Ea=29.54kJ/mol，表明反应速度随温度升高而增快。 关键词：生物柴油；桐油甲酯；酯化反应；酯交换反应；动力学 Abstract This paper studies the process and kinetics of catalyzing tung oil to produce biodiesel by a two-step catalytic process. Firstly, tung oil is esterified with potassium dichromate catalyst to produce tung oil methyl ester. Then, tung oil methyl ester is transesterified with potassium hydroxide catalyst to produce biodiesel. On this basis, the reaction conditions and kinetics were studied. The results showed that: (1) The type and amount of catalysts have a great influence on the reaction, and 0.5% and 0.8% of potassium dichromate and potassium hydroxide catalysts respectively are most suitable. (2) The temperature and reaction time also have a great influence on the reaction. The optimum reaction temperature is 60°C, and the optimum reaction time is 4 hours. (3) Under the optimal reaction conditions, the reaction rate obeys the first-order reaction kinetics, with the reaction kinetic parameters of k=0.03568 and Ea=29.54kJ/mol, indicating that the reaction rate increases with the increase of temperature. Keywords: biodiesel; tung oil methyl ester; esterification; transesterification; kinetics