基于氧杂蒽含氟二酐单体的聚酰亚胺薄膜的制备与性能研究.docxVIP

基于氧杂蒽含氟二酐单体的聚酰亚胺薄膜的制备与性能研究

目录

一、内容概要................................................3

1.研究背景..............................................3

2.研究意义..............................................4

3.研究内容与方法........................................5

二、实验材料与方法..........................................6

1.实验原料..............................................7

氧杂蒽.................................................8

含氟二酐单体...........................................9

聚酰亚胺前驱体........................................10

2.实验设备与仪器.......................................11

热风干燥箱............................................12

干法纺丝设备..........................................13

X射线衍射仪...........................................15

热重分析仪............................................16

机械性能测试机........................................17

三、氧杂蒽含氟二酐单体的合成与表征.........................18

1.合成路线设计.........................................18

2.单体合成过程.........................................19

3.表征方法.............................................20

红外光谱分析..........................................21

核磁共振氢谱分析......................................22

高分子电解质电化学表征................................23

四、聚酰亚胺薄膜的制备与结构表征...........................24

1.制备过程.............................................25

溶液配制..............................................26

干法纺丝工艺..........................................28

初步热处理............................................29

2.结构表征.............................................30

X射线衍射分析.........................................31

扫描电子显微镜观察....................................32

热稳定性分析..........................................33

五、聚酰亚胺薄膜的性能测试与分析...........................34

1.热性能测试...........................................35

差示扫描量热法........................................36

热膨胀系数测定........................................36

2.机械性能测试.........................................37

拉伸强度和弯曲强度