冷喷涂铜锌合金复合涂层的腐蚀行为研究.pdfVIP

《热加工工艺》2022年7月第51卷第14期

冷喷涂铜锌合金复合涂层的腐蚀行为研究

邵龙，吴惠舒，张留艳，揭晓华

（广东工业大学材料与能源学院，广东广州510006

摘要：研究了镁合金上低压冷喷涂法制备的铜锌合金复合涂层的结构和耐蚀性。采用低压冷喷涂技术在镁合金

表面制备铜锌合金复合涂层。通过微观观察、结合力测试、电化学极化法和电化学阻抗谱测试研究了该涂层的结构和腐

蚀行为。结果表明：采用低压冷喷涂法可在镁合金上制备铜锌合金复合涂层，涂层中合金颗粒发生大塑性变形后紧密结

合，涂层结构致密，孔隙率低。铜锌合金复合涂层与镁合金基体具有较强的结合性能，结合力测试得到的结合力超过23

MPa，且拉伸断口发生在涂层内部，涂层和基体间结合力强。铜锌合金复合涂层在盐溶液中具有较好的耐蚀性，其自腐蚀

电位明显高于镁合金基体的，自腐蚀电流显著小于基体的，长期浸泡腐蚀仍然保持较高的电阻，涂层长效防护效果优异。

关键词：冷喷涂；铜锌合金：涂层：腐蚀行为

DOI:10.14158/ki.1001-3814

中图分类号：TG174.4文献标识码：A文章编号：1001-3814(2022）14-0099-04

StudyonCorrosionBehaviorofCopperZincAlloyCompositeCoating

PreparedbyColdSpraying

SHAOLong,WUHuishu，ZHANGLiuyan,JIEXiaohua

Abstract

sprayingonmagnesiumalloyswerestudied.Thecopperzincalloycompositecoatingwaspreparedonthesurfaceof

magnesiumalloybylow-pressurecoldsprayingtechnology.Thestructureandcorrosionbehaviorofthecoatingwerestudied

bymicroscopicobservation

spectroscopytest.Theresultsshowthatthelow-pressurecoldsprayingmethodcanbeusedtopreparecopperzincalloy

compositecoatingsonmagnesiumalloys.Thealloyparticlesinthecoatingsaretightlybondedafterlargeplasticdeformation,

andthecoatingstructureisdenseandtheporosityislow.Thecopperzincalloycompositecoatinghasastrongbonding

propertywiththemagnesiumalloysubstrate.Thebondingforceobtainedbythebindingforetestexceeds23MPa,andthe

tensilefractureoccursinsidethecoating.Thebondingforcebetweenthecoatingandthesubstrateisstrong.Thecopperzinc

alloycompositecoatinghasbettercorrosionresistanceinsaltsolution.Itsself-corrosionpotentialissignificantlyhigherthan

thatofthemagnesiumalloysubstrate.Theself-corrosioncurrentissignificantlysmallerthanth