分析化学作业答案：配位滴定与金属离子测定方法.pdfVIP

Analyticalchemistry

Exercisesandsolutions

MaQuanhong

Slide1of87Analyticalchemistry:ExercisesandMaQuanhong

solution

Exercise

•QuantitativeChemicalAnalysis：P144:5.11(1)

lglgc(MY)+lgK−6

Y(H)eqMY

0.01

lg+23.2−615.2pH1.8or1.6

min

2

44

K10−44

−sp2.6610−11

[OH]

4+210−2

[Th]

pHmax14−pOH3.4

Slide2of87Analyticalchemistry:ExercisesandMaQuanhong

solution

Exercise

分析化学P127习题3

①lgKMgY’lgKMgY−lgY(H)8.69−4.654.04

②

lglgc(MgY)+lgK−6

Y(H)eqMgY

0.01

lg+8.69−60.39

2

∴pH≥10.2

∴在pH6时不能用EDTA滴定Mg2+

Slide3of87Analyticalchemistry:ExercisesandMaQuanhong

solution

4.3.6thecomplexationtitrationfor

mixturemetalions

•Exercise:CanthecontentofFe3+，Al3+，Ca2+andMg2+ina

mixturesolutionbedeterminedrespectivelybycomplexation

titrationmethod?Designtheexperimentalprogramincluding

thechoiceoftheconcentrationoftitrant,pHvalue,indicator

andtitrationmethod.(设计简要方案(包括滴定剂浓度、酸度、

指示剂，所需其他试剂及滴定方式)

Given:lgKFeY=25.1,lgKAlY=16.1,lgKCaY=10.69,

lgK=8.69,K(Fe(OH))=3.5×10-38,

MgY