硅烷偶联剂的偶联作用机理及其在密封胶中的应用.PDFVIP

化 学 与 黏 合 2013 年第35 卷第2 期 CHEMISTRY AND ADHESION ·63· 硅烷偶联剂的偶联作用机理及其在密封胶中的应用 * 杜慧翔，黄活阳，王文鹏，张雅洁 （广东新展化工新材料有限公司，广东 中山 528441） 摘要：硅烷偶联剂作为一种重要助剂，在密封胶、胶黏剂、金属防腐及涂料等领域都有广泛的应用。综述了硅烷偶联剂的偶 联作用机理，包括化学键合理论、变形层及拘束层理论、摩擦层理论及应力松弛假说等。介绍了硅烷偶联剂在密封胶领域的几 种典型应用方法，主要包括基材表面的底涂、填料颗粒的表面改性及作为助剂与基础聚合物共混等。讨论了不同使用条件下影 响硅烷偶联剂使用效果的因素，并对硅烷偶联剂的发展进行了展望。 关键词：硅烷偶联剂；偶联机理；密封胶 中图分类号：TQ436.6 文献标识码：A 文章编号：1001-0017（2013）02-0063-04 Coupling Mechanism of Silane Coupling Agent and Its Application in Sealant DU Hui-xiang, HUANG Huo-yang, WANG Wen-peng and ZHANG Ya-jie （Guangdong Xinzhan Silicone Co.,Ltd., Zhongshan 528441,China） Abstract ：As an important auxiliary, silane coupling agent is widely applied in many fields, such as sealant, adhesive, metal anticorrosion and coating. The coupling mechanism of silane coupling agent is introduced, including chemical bonding theory, deformation layer and constrain layer theory, frictional layer theory and stress relaxation hypothesis. The application methods of silane coupling agent in sealant are summarized, such as prime coat of substrate surface, surface modification of filler particle and alloying with basic polymers as an auxiliary. The factors which have effects on silane coupling agent under different conditions are discussed. And the development of silane coupling agent is presented. Key words ：Silane coupling agent; coupling mechanism; sealant 结构外，硅烷偶联剂还有双烷氧硅基硅烷偶联剂、阳 前 言 离子型硅烷偶联剂、潜在性氨基硅烷偶联剂、环状氮 杂硅烷偶联剂和含2个有机官能团的硅烷偶联剂等 硅烷偶联剂是一类同时含有有机官能团和可水