200882893845801锗玻璃.pdf

18 8 2008 8 Vol.18 No.8 The Chinese Journal of Nonferrous Metals Aug. 2008 1004-0609(2008)08-1504-08 ( 410083) CCl 40GeO -30SiO -12Al O -6BaO-6CaO-6MgO 4 2 2 2 3 OH3 338 /cm (3.0 µm)Gauss5 OH1.71 /cm OH0.25 /cmDTAXRD OH TB 321 A Low OH content germanate glass prepared by batch soaking process in CCl4 XIAO Zhuo-hao, CHEN Yuan-yuan, ZUO Cheng-gang, LU An-xian (School of Materials Science and Engineering, Central South University, Changsha 410083, China) Abstract: 40GeO -30SiO -12Al O -6BaO-6CaO-6MgO glass was prepared by using batch soaking process with CCl as 2 2 2 3 4 dehydration agent. The influence of this process on the infrared transmittance and crystallization behavior of the germanium glass was investigated. The results show that the infrared spectra contains a single band at approximately 3 338 /cm for the germanate glass. This broad absorption band is deconvoluted into five bands and some possible reasons for each band have been given. The absorption coefficient of hydroxyl in the germanate glass prepared by conventional melt quenching technique is 1.71 /cm while that of the one prepared by batch soaking process in CCl4 is 0.25 /cm. The analyses of DTA and XRD indicate that the glass prepared by batch soaking process crystallizes at lower temperature and has bigger crystallization rate for the residual chlorine acting as a nucleation agent in the interspaces of the glass netwo