BISPHENYLENECOSAN as highly selective Cs+ extraction agent:(BISPHENYLENECOSAN是高度选择性Cs +萃取剂).pdfVIP
- 1、本文档共6页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
- 5、该文档为VIP文档,如果想要下载,成为VIP会员后,下载免费。
- 6、成为VIP后,下载本文档将扣除1次下载权益。下载后,不支持退款、换文档。如有疑问请联系我们。
- 7、成为VIP后,您将拥有八大权益,权益包括:VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
- 8、VIP文档为合作方或网友上传,每下载1次, 网站将根据用户上传文档的质量评分、类型等,对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档
查看更多
Journal of Radioanalytical and Nuclear Chemistry, Vol.224, Nos 1-2 (1997) 89-94
B I S P H E N Y L E N E C O S A N as highly selective Cs § extraction agent
P. Seluck~, N. V. Sistkovli, J. Rais
Nuclear Research Institute, plc, 25068 ~e~I, CzechRepublic
(Received July 7, 1997)
A new reagent for the highly selective extraction of cesium (e-l,7-2,2)4,8-8,4-(bis-l.t-o-phenylene)bisdiearboUidocobalt(1-)ate, [(C2B9H9)2(C6H4)2Co]- ,
abbreviated as BISPHECOSAN is described in this paper. The choice of organic solvent and solubilizer, dependence of distribution ratio of Cs+ on acidity
and other parameters are studied. The extraction mechanism based on selective binding of Cs+ cation between two phenylene rings is presented and factors
influencing the chemical stability of the reagent are determined.
Introduction well known solubilizers used in manufacturing ion
selective electrodes, i.e., di(ethylhexyl)adipate and
Dicarbollylcobaltate anions have proven as an effective di(ethylhexyl)sebacate in the study. All the above
extractant for Cs § cations. 1Their use enables the separation mentioned compounds enable the dissolution of
of cesium in highly acidic media and the respective BISPHECOSAN in non polar aromatic solvents like
technology for the separation of 137Csand 9~ from Purex toluene.
nuclear waste prol~osed and develop
您可能关注的文档
- Biotechnology for Insurers Reflections and Suggestions:(保险公司生物技术的反思和建议).pdf
- Biotransformation of (+)limonene and (-)piperitone by yeasts and yeast-like fungi:(生物转化的柠檬烯(+)和(-)piperitone酵母和类酵母菌).pdf
- Bi-phasic production of a-amylase of Bacillus flavothermusin batch fermentation:(Bi-phasic a-amylase杆菌flavothermusin批发酵的生产).pdf
- Biphasic Testosterone Delivery Profile Observed with Two Different Transdermal Formulations:(两相的睾酮交付剖面观察到两个不同的皮肤配方).pdf
- Bipiperidyl and Quinolizidine Alkaloids in Fruits of Viscum cruciatum Hemiparasitic on Retama sphaerocarpa:(Bipiperidyl Quinolizidine生物碱在槲寄生的果实cruciatum Hemiparasitic在Retama sphaerocarpa).pdf
- Birefringence thermal analysis of liquid crystalline monomers and their photopolymers:(双折射液晶单体的热分析及其光敏聚合物).pdf
- Birkhoff's HSP-theorem for cumulative logic programs:(比尔科夫的HSP-theorem累积逻辑程序).pdf
- Bis(trifluoromethyl)-containing 1-azatricycloheptanes:(Bis(trifluoromethyl)包含1-azatricycloheptanes).pdf
- Bismuth:(铋).pdf
- Bis-para-semiquinoid type double cyclopalladation in the series of six-membered two-nitrogen bridged annulene-dihydroannulene ligands:(Bis-para-semiquinoid类型双cyclopalladation一系列六元two-nitrogen架桥annulene-dihydroannulene配体).pdf
文档评论(0)