改进的光催化法制备金属钯膜的气体渗透.pdfVIP

改进的光催化法制备金属钯膜的气体渗透性能研究 李雪 范益群 金万勤 黄彦 徐南平* （南京工业大学膜科学技术研究所，江苏省材料化学工程重点实验室，江苏南京210009 ） 摘 要 本文在光催化沉积法(PCD)的基础上进行了改进。基本原理是在紫外光直接照射下，使 TiO2 过渡层 与Pd (II)液膜之间发生光催化反应。辅助SEM、EDS 表征方法对所制的钯膜分析表明,该方法制得的钯膜很薄， 仅为 0.4 μm 左右；在 612.5~704.5K 和 0.05~0.12MPa 下进行气体渗透试验，氢气的渗透性与选择性分别为 4.8×10-6 mol.m-2.s-1.Pa-1 和 120 。 关键词 钯膜 光催化 TiO2 氢气渗透 Permeation of palladium membranes by an improved photocatalytic deposition LI Xue, FAN Yiqun, JIN Wanqin, Huang Yan, XU Nanping (Membrane Science Technology Research Center, Nanjing University of Technology, Nanjing 210009,China) Abstract In order to optimize ultra-thin palladium membrane integrity, a improved photocatalytic deposition is developed on the base of photocatalytic deposition (PCD) for the Pd/TiO2 composite membranes. The mechanism of the modified PCD method is interpreted by the photocatalytic reaction at the TiO2 semiconductor layer/Pd (II) liquid film interface by directly irradiating. An ultra-thin tube palladium membrane with the thickness of about 0.4 µm on the TiO2 semiconductor membrane has been fabricated by the modified photocatalytic deposition.The gas permeation experiment was conducted under 612.5 ~704.5 K and 0.05~0.12 MPa. The hydrogen permeability -6 -2 -1 -1 and selectivity of H /N were 4.8×10 mol.m .s .Pa and 120 at 704.5 K, respectively. 2 2 Keywords: Palladium Membrane, Photocatalytic Deposition, TiO2, hydrogen separation 引 言 金属钯膜是最早用于分离氢气的无机膜，近年来支撑钯及钯合金膜的制备与应用已成为 *通讯联系人：徐南平 Tel.: 025 Fax: 025 Email: npxu@njut.edu.cn 第一作者：李雪，女，27 岁，博士生. 基金项目：国家基础研究计划(No. 2003CB615707)，国家自然科学基金(NNSFC, No. 1