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Evaluation of a New Environmentally
Friendly Chelating Agent for
High-Temperature Applications
M.A. Mahmoud and H.A. Nasr-El-Din, SPE, Texas AM University; and C.A. De Wolf,
J.N. LePage, SPE, and J.H. Bemelaar, AkzoNobel
Summary was found to be a function of the rock composition, reaction
Matrix acidizing is used in carbonate formations to create worm- temperature, and the pore-size distribution of the reservoir rock.
holes that connect the formation to the wellbore. Hydrochloric acid A problem occurs if the required optimum injection rate is greater
(HCl), organic acids, or mixtures of these acids are typically used than the maximum acid-injection rate. In this case, HCl cannot be
in matrix-acidizing treatments of carbonate reservoirs. However, used because it will fracture the formation. Therefore, stimulation
the use of these acids in deep wells has some major drawbacks, fluids other than HCl-based fluids, such as chelating agents, need
including high and uncontrolled reaction rates and corrosion to to be used to achieve deep and uniform penetration and eliminate
well tubulars, especially those made of chromium-based tubulars face-dissolution problems.
(Cr-13 and duplex steel); and these problems become severe at high Another problem encountered during stimulation using HCl-
temperatures. To overcome problems associated with strong acids, based fluids is the high corrosion rate of these fluids to the well
chelating agents were introduced and used in the field. However, tubulars. Well tubular
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